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Periodic Table and Periodicity question

2023 · 31 Jan · Shift 2 · Q5
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  5. /2023 · 31 Jan · Shift 2 · Q5

Periodic Table and Periodicity question

2023 · 31 Jan · Shift 2 · Q5

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Which of the following elements have half-filled f-orbitals in their ground state? (Given : atomic number Sm=62;Eu=63;Tb=65;Gd=64,Pm=61\mathrm{Sm}=62 ; \mathrm{Eu}=63 ; \mathrm{Tb}=65 ; \mathrm{Gd}=64, \mathrm{Pm}=61Sm=62;Eu=63;Tb=65;Gd=64,Pm=61) A. Sm\mathrm{Sm}Sm B. Eu C. Tb\mathrm{Tb}Tb D. Gd E. Pm\mathrm{Pm}Pm Choose the correct answer from the options given below :
  1. A
    B and D only
  2. B
    A and BBB only
  3. C
    CCC and D\mathrm{D}D only
  4. D
    A and E only
View written solutionFree

Correct answer: A

  1. Meaning of half-filled fff-orbitals

A half-filled fff-subshell means: f7f^7f7 because the fff-subshell has 7 orbitals and can hold a maximum of 14 electrons.

So we need to identify which given elements have ground-state configuration containing 4f74f^74f7.


  1. Write ground-state electronic configurations

For lanthanoids, the relevant part is 4f4f4f, 5d5d5d, and 6s6s6s.

  • Pm (Z=61)(Z=61)(Z=61): [Xe] 4f56s2[Xe] \, 4f^5 6s^2[Xe]4f56s2

  • Sm (Z=62)(Z=62)(Z=62): [Xe] 4f66s2[Xe] \, 4f^6 6s^2[Xe]4f66s2

  • Eu (Z=63)(Z=63)(Z=63): [Xe] 4f76s2[Xe] \, 4f^7 6s^2[Xe]4f76s2 Here, the fff-subshell is half-filled.

  • Gd (Z=64)(Z=64)(Z=64): [Xe] 4f75d16s2[Xe] \, 4f^7 5d^1 6s^2[Xe]4f75d16s2 Here also, the 4f4f4f-subshell is half-filled.

  • Tb (Z=65)(Z=65)(Z=65): [Xe] 4f96s2[Xe] \, 4f^9 6s^2[Xe]4f96s2 (more precisely often written as 4f96s24f^9 6s^24f96s2, sometimes with 5d05d^05d0) This is not half-filled.


  1. Check each element
  • A. Sm: 4f64f^64f6 → not half-filled
  • B. Eu: 4f74f^74f7 → half-filled
  • C. Tb: 4f94f^94f9 → not half-filled
  • D. Gd: 4f74f^74f7 → half-filled
  • E. Pm: 4f54f^54f5 → not half-filled

So the correct elements are: Eu and Gd\boxed{\text{Eu and Gd}}Eu and Gd​


  1. Match with given options

Option A: B and D only

This corresponds to Eu and Gd only, which is correct.


  1. Comparison with stored correct answer

Stored correct answer = A

Our derived answer = A

So they agree.

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