JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Which of the following elements have half-filled f-orbitals in their ground state? (Given : atomic number ) A. B. Eu C. D. Gd E. Choose the correct answer from the options given below :
- AB and D only
- BA and only
- Cand only
- DA and E only
View written solutionFree
Correct answer: A
- Meaning of half-filled -orbitals
A half-filled -subshell means: because the -subshell has 7 orbitals and can hold a maximum of 14 electrons.
So we need to identify which given elements have ground-state configuration containing .
- Write ground-state electronic configurations
For lanthanoids, the relevant part is , , and .
-
Pm :
-
Sm :
-
Eu : Here, the -subshell is half-filled.
-
Gd : Here also, the -subshell is half-filled.
-
Tb : (more precisely often written as , sometimes with ) This is not half-filled.
- Check each element
- A. Sm: → not half-filled
- B. Eu: → half-filled
- C. Tb: → not half-filled
- D. Gd: → half-filled
- E. Pm: → not half-filled
So the correct elements are:
- Match with given options
Option A: B and D only
This corresponds to Eu and Gd only, which is correct.
- Comparison with stored correct answer
Stored correct answer = A
Our derived answer = A
So they agree.
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