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Periodic Table and Periodicity question

2022 · 24 Jun · Shift 1 · Q5
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  5. /2022 · 24 Jun · Shift 1 · Q5

Periodic Table and Periodicity question

2022 · 24 Jun · Shift 1 · Q5

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Given below are the oxides: Na2ONa_2ONa2​O, As2O3As_2O_3As2​O3​, N2ON_2ON2​O, NONONO and Cl2O7Cl_2O_7Cl2​O7​ Number of amphoteric oxides is :
  1. A
    0
  2. B
    1
  3. C
    2
  4. D
    3
View written solutionFree

Correct answer: B

  1. Classify each oxide by acid-base behavior

We analyze the given oxides one by one:

  • Na2ONa_2ONa2​O
  • As2O3As_2O_3As2​O3​
  • N2ON_2ON2​O
  • NONONO
  • Cl2O7Cl_2O_7Cl2​O7​

  1. Na2ONa_2ONa2​O

Na2ONa_2ONa2​O is an oxide of an alkali metal. Alkali metal oxides are basic oxides.

Na2O+H2O→2NaOHNa_2O + H_2O \rightarrow 2NaOHNa2​O+H2​O→2NaOH

So, Na2ONa_2ONa2​O is basic, not amphoteric.


  1. As2O3As_2O_3As2​O3​

As2O3As_2O_3As2​O3​ (arsenious oxide) shows both acidic and basic character, so it is amphoteric.

It can react with acids as well as with bases.

Hence, As2O3As_2O_3As2​O3​ is amphoteric.


  1. N2ON_2ON2​O

N2ON_2ON2​O is a neutral oxide. It is neither acidic nor basic.

So, N2ON_2ON2​O is not amphoteric.


  1. NONONO

NONONO is also a neutral oxide.

So, NONONO is not amphoteric.


  1. Cl2O7Cl_2O_7Cl2​O7​

Cl2O7Cl_2O_7Cl2​O7​ is the anhydride of perchloric acid:

Cl2O7+H2O→2HClO4Cl_2O_7 + H_2O \rightarrow 2HClO_4Cl2​O7​+H2​O→2HClO4​

Thus, it is a strongly acidic oxide, not amphoteric.


  1. Count amphoteric oxides

Only As2O3As_2O_3As2​O3​ is amphoteric.

Therefore, the number of amphoteric oxides = 1.


  1. Compare with options
  • A: 000
  • B: 111 ✅
  • C: 222
  • D: 333

So, the correct option is B.

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