JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : The ionic radii of and are same. Reason (R) : Both and are isoelectronic species. In the light of the above statements, choose the correct answer from the options given below.
- ABoth (A) and (R) are true and (R) is the correct explanation of (A).
- BBoth (A) and (R) are true but (R) is not the correct explanation of (A).
- C(A) is true but (R) is false.
- D(A) is false but (R) is true.
View written solutionFree
Correct answer: D
- Check the Reason (R): Are and isoelectronic?
-
Oxygen has atomic number .
-
In , it gains electrons:
-
Magnesium has atomic number .
-
In , it loses electrons:
So, both ions have electrons.
Therefore, and are isoelectronic species.
Hence, Reason (R) is true.
- Check the Assertion (A): Are the ionic radii of and same?
Although they are isoelectronic, isoelectronic species do not necessarily have the same radius.
For an isoelectronic series, radius depends on nuclear charge:
- Greater nuclear charge stronger attraction on the same number of electrons
- Hence, smaller radius
Now compare nuclear charges:
- For : nuclear charge =
- For : nuclear charge =
Since has much higher nuclear charge, it pulls the same 10 electrons more strongly. Thus,
So, their ionic radii are not same.
Hence, Assertion (A) is false.
- Evaluate the options
- A: Both true, and R explains A False
- B: Both true, but R not explanation False
- C: A true, R false False
- D: A false, R true Correct
- Final Answer
The correct option is:
- Comparison with stored correct answer
Stored correct answer:
My derived answer also is , so they agree.
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