Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Periodic Table and Periodicity question

2023 · 30 Jan · Shift 2 · Q11
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Periodic Table and Periodicity
  5. /2023 · 30 Jan · Shift 2 · Q11

Periodic Table and Periodicity question

2023 · 30 Jan · Shift 2 · Q11

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
Bond dissociation energy of "E−HE-HE−H" bond of the "H2E\mathrm{H}_{2} \mathrm{E}H2​E" hydrides of group 16 elements (given below), follows order. A. O\mathrm{O}O B. S\mathrm{S}S C. SeSeSe D. Te\mathrm{Te}Te Choose the correct from the options given below:
  1. A
    A>B>C>D\mathrm{A}\gt \mathrm{B}\gt \mathrm{C}\gt \mathrm{D}A>B>C>D
  2. B
    D>C>B>A\mathrm{D}\gt \mathrm{C}\gt \mathrm{B}\gt \mathrm{A}D>C>B>A
  3. C
    B>A>C>D\mathrm{B}\gt \mathrm{A}\gt \mathrm{C}\gt \mathrm{D}B>A>C>D
  4. D
    A>B>D>C\mathrm{A}\gt \mathrm{B}\gt \mathrm{D}\gt \mathrm{C}A>B>D>C
View written solutionFree

Correct answer: A

  1. We need the order of bond dissociation energy of the E−HE-HE−H bond in group 16 hydrides:

H2O,H2S,H2Se,H2Te\mathrm{H_2O,\\ H_2S,\\ H_2Se,\\ H_2Te}H2​O,H2​S,H2​Se,H2​Te

where:

  • A=OA = OA=O
  • B=SB = SB=S
  • C=SeC = SeC=Se
  • D=TeD = TeD=Te
  1. Down group 16, the size of the central atom EEE increases:

O<S<Se<TeO < S < Se < TeO<S<Se<Te

  1. As atomic size increases, the overlap between the orbitals of EEE and HHH becomes poorer.
  • O−HO-HO−H bond has the best overlap and is shortest, so it is strongest.
  • Moving down the group, S−HS-HS−H, Se−HSe-HSe−H, and Te−HTe-HTe−H bonds become progressively longer and weaker.

Therefore, bond dissociation energy decreases down the group:

O−H>S−H>Se−H>Te−HO-H > S-H > Se-H > Te-HO−H>S−H>Se−H>Te−H

  1. Translating this into the given labels:

A>B>C>DA > B > C > DA>B>C>D

  1. Now check the options:
  • Option A: A>B>C>DA > B > C > DA>B>C>D ✅
  • Option B: D>C>B>AD > C > B > AD>C>B>A ❌
  • Option C: B>A>C>DB > A > C > DB>A>C>D ❌
  • Option D: A>B>D>CA > B > D > CA>B>D>C ❌

Hence, the correct option is A.

PreviousNext

More from Periodic Table and Periodicity

  • The correct increasing order of the ionic radii is2023 · MCQ
  • Which of the following elements have half-filled f-orbitals in their ground state? (Given : atomic number Sm=62;Eu=63;Tb=65;Gd=64,Pm=61) A. Sm B. Eu C. Tb D. Gd E.…2023 · MCQ
  • Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R) Assertion (A): The first ionization enthalpy of 3 d series elements is more than that of group 2 metals Reason (R): In 3d…2023 · MCQ
  • Given below are the oxides: Na2​O, As2​O3​, N2​O, NO and Cl2​O7​ Number of amphoteric oxides is :2022 · MCQ
  • The IUPAC nomenclature of an element with electronic configuration [Rn] 5f146d17s2 is :2022 · MCQ
  • The first ionization enthalpies of Be, B, N and O follow the order2022 · MCQ
  • The correct order of electron gain enthalpies of Cl, F, Te and Po is2022 · MCQ
  • Given two statements below : Statement I : In Cl2​ molecule the covalent radius is double of the atomic radius of chlorine. Statement II : Radius of anionic species is always greater than their parent atomic radius. Choose the…2022 · MCQ