JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The electronic configuration with the highest ionization enthalpy is :
- A[Ne] 3s2 3p1
- B[Ne] 3s2 3p2
- C[Ne] 3s2 3p3
- D[Ar] 3d10 4s2 4p3
View written solutionFree
Correct answer: C
- Identify the elements from the electronic configurations
- A: corresponds to Aluminium (Al)
- B: corresponds to Silicon (Si)
- C: corresponds to Phosphorus (P)
- D: corresponds to Arsenic (As)
- Recall the trend of ionization enthalpy
Ionization enthalpy generally:
- increases across a period from left to right,
- decreases down a group due to increase in atomic size and shielding.
Also, a half-filled subshell has extra stability.
- Compare the given configurations
Option A: (Al)
- Relatively lower ionization enthalpy.
- First electron removed from a electron.
Option B: (Si)
- Higher than Al because nuclear charge increases across the period.
Option C: (P)
- This has a half-filled configuration, which is especially stable.
- Therefore, removing one electron requires extra energy.
- So its ionization enthalpy is higher than Si and Al.
Option D: (As)
- Also has a half-filled configuration.
- But As lies below P in the same group.
- Ionization enthalpy decreases down the group because of larger size and greater shielding.
- Therefore, As has lower ionization enthalpy than P.
- Conclusion
Among all the given configurations, the one with the highest ionization enthalpy is
So the correct option is C.
- Comparison with stored correct answer
- Derived answer: C
- Stored correct answer: C
They match.
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