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Periodic Table and Periodicity question

2017 · 9 Apr · Shift 1 · Q16
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Periodic Table and Periodicity question

2017 · 9 Apr · Shift 1 · Q16

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The electronic configuration with the highest ionization enthalpy is :
  1. A
    [Ne] 3s2 3p1
  2. B
    [Ne] 3s2 3p2
  3. C
    [Ne] 3s2 3p3
  4. D
    [Ar] 3d10 4s2 4p3
View written solutionFree

Correct answer: C

  1. Identify the elements from the electronic configurations
  • A: [Ne] 3s23p1[\mathrm{Ne}]\,3s^2 3p^1[Ne]3s23p1 corresponds to Aluminium (Al)
  • B: [Ne] 3s23p2[\mathrm{Ne}]\,3s^2 3p^2[Ne]3s23p2 corresponds to Silicon (Si)
  • C: [Ne] 3s23p3[\mathrm{Ne}]\,3s^2 3p^3[Ne]3s23p3 corresponds to Phosphorus (P)
  • D: [Ar] 3d104s24p3[\mathrm{Ar}]\,3d^{10}4s^2 4p^3[Ar]3d104s24p3 corresponds to Arsenic (As)

  1. Recall the trend of ionization enthalpy

Ionization enthalpy generally:

  • increases across a period from left to right,
  • decreases down a group due to increase in atomic size and shielding.

Also, a half-filled subshell has extra stability.


  1. Compare the given configurations

Option A: [Ne] 3s23p1[\mathrm{Ne}]\,3s^2 3p^1[Ne]3s23p1 (Al)

  • Relatively lower ionization enthalpy.
  • First electron removed from a 3p3p3p electron.

Option B: [Ne] 3s23p2[\mathrm{Ne}]\,3s^2 3p^2[Ne]3s23p2 (Si)

  • Higher than Al because nuclear charge increases across the period.

Option C: [Ne] 3s23p3[\mathrm{Ne}]\,3s^2 3p^3[Ne]3s23p3 (P)

  • This has a half-filled 3p33p^33p3 configuration, which is especially stable.
  • Therefore, removing one electron requires extra energy.
  • So its ionization enthalpy is higher than Si and Al.

Option D: [Ar] 3d104s24p3[\mathrm{Ar}]\,3d^{10}4s^2 4p^3[Ar]3d104s24p3 (As)

  • Also has a half-filled p3p^3p3 configuration.
  • But As lies below P in the same group.
  • Ionization enthalpy decreases down the group because of larger size and greater shielding.
  • Therefore, As has lower ionization enthalpy than P.

  1. Conclusion

Among all the given configurations, the one with the highest ionization enthalpy is

[Ne] 3s23p3[\mathrm{Ne}]\,3s^2 3p^3[Ne]3s23p3

So the correct option is C.


  1. Comparison with stored correct answer
  • Derived answer: C
  • Stored correct answer: C

They match.

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