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Periodic Table and Periodicity question

2016 · 10 Apr · Shift 1 · Q13
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Periodic Table and Periodicity question

2016 · 10 Apr · Shift 1 · Q13

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The following statements concern elements in the periodic table. Which of the following is true ?
  1. A
    All the elements in Group 17 are gases.
  2. B
    The Group 13 elements are all metals.
  3. C
    Elements of Group 16 have lower ionization enthalpy values compared to those of Group 15 in the corresponding periods.
  4. D
    For Group 15 elements, the stability of + 5 oxidation state increases down the group.
View written solutionFree

Correct answer: C

  1. Check option A: Group 17 are all gases?

Group 17 elements are halogens: F, Cl, Br, I, At\mathrm{F,\ Cl,\ Br,\ I,\ At}F, Cl, Br, I, At.
At room temperature:

  • F2\mathrm{F_2}F2​ and Cl2\mathrm{Cl_2}Cl2​ are gases,
  • Br2\mathrm{Br_2}Br2​ is a liquid,
  • I2\mathrm{I_2}I2​ is a solid.

So, all Group 17 elements are not gases.
Hence, A is false.

  1. Check option B: Group 13 elements are all metals?

Group 13 elements are B, Al, Ga, In, Tl\mathrm{B,\ Al,\ Ga,\ In,\ Tl}B, Al, Ga, In, Tl.
Here, boron (B\mathrm{B}B) is a metalloid, not a metal.

So, all Group 13 elements are not metals.
Hence, B is false.

  1. Check option C: Group 16 elements have lower ionization enthalpy than Group 15 elements in the same period?

Compare electronic configurations:

  • Group 15: ns2np3ns^2 np^3ns2np3 (half-filled ppp-subshell, extra stability)
  • Group 16: ns2np4ns^2 np^4ns2np4

Because half-filled subshells are relatively more stable, removing an electron from Group 15 requires more energy than from Group 16 in the same period.

Therefore, Ionization enthalpy of Group 16<Ionization enthalpy of Group 15\text{Ionization enthalpy of Group 16} < \text{Ionization enthalpy of Group 15}Ionization enthalpy of Group 16<Ionization enthalpy of Group 15 within the same period.

Hence, C is true.

  1. Check option D: For Group 15, stability of +5+5+5 oxidation state increases down the group?

In Group 15 (N,P,As,Sb,Bi\mathrm{N, P, As, Sb, Bi}N,P,As,Sb,Bi), due to the inert pair effect, the lower oxidation state +3+3+3 becomes more stable down the group, while the higher oxidation state +5+5+5 becomes less stable.

So, the stability of +5+5+5 oxidation state decreases down the group.

Hence, D is false.


Final conclusion

Only option C is correct.

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