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Periodic Table and Periodicity question

2004 · Shift 0 · Q61
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Periodic Table and Periodicity question

2004 · Shift 0 · Q61

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The formation of the oxide ion O2−O^{2-}O2−(g) requires first an exothermic and then an endothermic step as shown below OOO(g) + e−e^-e− = O(g)−ΔO_{(g)}^{-}\DeltaO(g)−​Δ Ho = -142 kJmol-1 O(g)−O_{(g)}^{-}O(g)−​+ e−e^-e− =O(g)2−ΔO_{(g)}^{2-}\DeltaO(g)2−​Δ Ho = 844 kJmol-1 This because
  1. A
    O−O^-O− ion will tend to resist the addition of another electron
  2. B
    Oxygen has high electron affinity
  3. C
    Oxygen is more electronegative
  4. D
    O−O^-O− ion has comparatively larger size than oxygen atom
View written solutionFree

Correct answer: A

  1. Identify the two steps

    Formation of O2−(g)O^{2-}(g)O2−(g) occurs in two successive electron-gain steps:

    O(g)+e−→O−(g)ΔH∘=−142 kJ mol−1O(g)+e^- \rightarrow O^-(g) \qquad \Delta H^\circ=-142\ \text{kJ mol}^{-1}O(g)+e−→O−(g)ΔH∘=−142 kJ mol−1

    O−(g)+e−→O2−(g)ΔH∘=+844 kJ mol−1O^-(g)+e^- \rightarrow O^{2-}(g) \qquad \Delta H^\circ=+844\ \text{kJ mol}^{-1}O−(g)+e−→O2−(g)ΔH∘=+844 kJ mol−1

  2. Interpret the signs of enthalpy change

    • First step is exothermic: energy is released when neutral oxygen gains one electron.
    • Second step is endothermic: energy must be supplied to add an electron to the already negatively charged ion O−O^-O−.
  3. Reason for the second step being endothermic

    In the second step, an incoming electron is being added to an ion that already has a negative charge.

    Hence, the incoming electron experiences electrostatic repulsion from O−O^-O−. Therefore, O−O^-O− resists the addition of another electron, and energy is required.

  4. Check the options

    A: O−O^-O− ion will tend to resist the addition of another electron
    This is correct. The second electron is added against electron-electron repulsion, so the process is endothermic.

    B: Oxygen has high electron affinity
    This explains why the first electron addition is exothermic, but not why the second is endothermic.

    C: Oxygen is more electronegative
    Electronegativity concerns attraction of bonding electrons, not directly the reason for the positive second electron gain enthalpy.

    D: O−O^-O− ion has comparatively larger size than oxygen atom
    Though O−O^-O− is larger than OOO, this is not the main reason for the endothermic second step. The key factor is repulsion due to negative charge.

  5. Conclusion

    The correct option is:

    A\boxed{A}A​

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