- Aion will tend to resist the addition of another electron
- BOxygen has high electron affinity
- COxygen is more electronegative
- Dion has comparatively larger size than oxygen atom
View written solutionFree
Correct answer: A
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Identify the two steps
Formation of occurs in two successive electron-gain steps:
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Interpret the signs of enthalpy change
- First step is exothermic: energy is released when neutral oxygen gains one electron.
- Second step is endothermic: energy must be supplied to add an electron to the already negatively charged ion .
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Reason for the second step being endothermic
In the second step, an incoming electron is being added to an ion that already has a negative charge.
Hence, the incoming electron experiences electrostatic repulsion from . Therefore, resists the addition of another electron, and energy is required.
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Check the options
A: ion will tend to resist the addition of another electron
This is correct. The second electron is added against electron-electron repulsion, so the process is endothermic.B: Oxygen has high electron affinity
This explains why the first electron addition is exothermic, but not why the second is endothermic.C: Oxygen is more electronegative
Electronegativity concerns attraction of bonding electrons, not directly the reason for the positive second electron gain enthalpy.D: ion has comparatively larger size than oxygen atom
Though is larger than , this is not the main reason for the endothermic second step. The key factor is repulsion due to negative charge. -
Conclusion
The correct option is:
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