- A- block
- B- block
- CRadioactive series
- DHigh atomic masses.
View written solutionFree
Correct answer: B
-
Interpret the statement
The phrase "reduction in atomic size with increase in atomic number" refers to a situation where, as we move across a series of elements, the atomic radii decrease instead of increasing.
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Recall the relevant periodic trend
This behavior is especially characteristic of the lanthanoids due to lanthanoid contraction.
- In the lanthanoid series, electrons are added to the subshell.
- The electrons shield the nuclear charge very poorly.
- Therefore, with increasing atomic number, the effective nuclear charge felt by outer electrons increases.
- As a result, the atomic size gradually decreases.
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Match with the given options
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A: -block
Not generally described by this special contraction phenomenon. -
B: -block
Correct, because the lanthanoids belong to the -block and show a steady decrease in atomic size with increasing atomic number. -
C: Radioactive series
Not a periodic trend classification for atomic size reduction. -
D: High atomic masses
High atomic mass is not the reason or the characteristic series showing this trend.
-
-
Conclusion
The reduction in atomic size with increase in atomic number is characteristic of -block elements (specifically lanthanoids).
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Comparison with stored correct answer
- Derived answer: B
- Stored correct answer: D
These do not match. The stored answer appears incorrect because the described trend is the well-known lanthanoid contraction, which is a property of the -block elements, not of elements with high atomic masses.
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