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Haloalkanes and Haloarenes question

2024 · 30 Jan · Shift 1 · Q18
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Haloalkanes and Haloarenes question

2024 · 30 Jan · Shift 1 · Q18

JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : CH2=CH−CH2−Cl\mathrm{CH}_2=\mathrm{CH}-\mathrm{CH}_2-\mathrm{Cl}CH2​=CH−CH2​−Cl is an example of allyl halide. Reason (R) : Allyl halides are the compounds in which the halogen atom is attached to sp2\mathrm{sp}^2sp2 hybridised carbon atom. In the light of the above statements, choose the most appropriate answer from the options given below :
  1. A
    (A) is true but (R) is false
  2. B
    (A) is false but (R) is true
  3. C
    Both (A) and (R) are true but (R) is not the correct explanation of (A)
  4. D
    Both (A) and (R) are true and (R) is the correct explanation of (A)
View written solutionFree

Correct answer: A

  1. Identify the given compound

    The compound is: CH2=CH−CH2−Cl\mathrm{CH_2=CH-CH_2-Cl}CH2​=CH−CH2​−Cl

    This is allyl chloride.

    In an allylic halide, the halogen is attached to the carbon atom adjacent to a carbon-carbon double bond.

  2. Check Assertion (A)

    Assertion says: CH2=CH−CH2−Cl\mathrm{CH_2=CH-CH_2-Cl}CH2​=CH−CH2​−Cl is an example of allyl halide.

    This is true, because the chlorine is attached to the carbon next to the double bond.

  3. Check Reason (R)

    Reason says: Allyl halides are compounds in which the halogen atom is attached to an sp2sp^2sp2 hybridised carbon atom.

    This is false.

    In allyl halides, the halogen is attached to an allylic carbon, which is typically sp3sp^3sp3 hybridised, not sp2sp^2sp2.

    For example, in CH2=CH−CH2−Cl\mathrm{CH_2=CH-CH_2-Cl}CH2​=CH−CH2​−Cl the carbon bearing Cl is the CH2\mathrm{CH_2}CH2​ carbon, and it is sp3sp^3sp3 hybridised.

  4. Conclusion

    • Assertion (A): True
    • Reason (R): False

    Therefore, the correct option is: A: (A) is true but (R) is false

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