Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Haloalkanes and Haloarenes question

2022 · 28 Jun · Shift 1 · Q9
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Haloalkanes and Haloarenes
  5. /2022 · 28 Jun · Shift 1 · Q9

Haloalkanes and Haloarenes question

2022 · 28 Jun · Shift 1 · Q9

JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
Which one of the following compounds is inactive towards SN1 reaction?
  1. A
    JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Haloalkanes and Haloarenes Question 75 English Option 1
  2. B
    JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Haloalkanes and Haloarenes Question 75 English Option 2
  3. C
    JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Haloalkanes and Haloarenes Question 75 English Option 3
  4. D
    JEE Main 2022 (Online) 28th June Morning Shift Chemistry - Haloalkanes and Haloarenes Question 75 English Option 4
View written solutionFree

Correct answer: C

The question asks which compound is inactive towards an SN1S_N1SN​1 reaction, but the actual structures/options for A, B, C, D are missing in the prompt.

For an SN1S_N1SN​1 reaction, the key requirement is formation of a reasonably stable carbocation after the leaving group departs.

1. Principle of SN1S_N1SN​1 reactivity

The rate-determining step is: R−LG→R++LG−R-LG \rightarrow R^+ + LG^-R−LG→R++LG− So, compounds that can form stable carbocations undergo SN1S_N1SN​1 easily.

Carbocation stability order is generally: 3∘>2∘>1∘>CH3+3^\circ > 2^\circ > 1^\circ > CH_3^+3∘>2∘>1∘>CH3+​ Also:

  • Benzylic and allylic halides are very reactive in SN1S_N1SN​1 due to resonance stabilization.
  • Vinylic and aryl halides are generally inactive towards SN1S_N1SN​1 because forming a vinyl or phenyl cation is highly unstable.

2. What kind of compound is usually inactive?

Typical compounds inactive towards SN1S_N1SN​1 are:

  • chlorobenzene, bromobenzene, etc. (Ar−X)(Ar-X)(Ar−X)
  • vinyl chloride, vinyl bromide, etc. (CH2=CH−X)(CH_2=CH-X)(CH2​=CH−X)

3. Issue with the given question

Since the actual option structures are not shown, it is not possible to determine definitively which among A, B, C, and D is the inactive compound.

4. Comparison with stored answer

The stored correct answer is C. Since the options are absent, I cannot independently verify whether option C is indeed the aryl/vinylic halide or some other SN1S_N1SN​1-inactive substrate.

Thus, based strictly on the provided data, the question is incomplete.

PreviousNext

More from Haloalkanes and Haloarenes

  • The major product of the following reaction contains ​ bromine atom(s). Includes diagram2022 · Numerical
  • In the above reaction 'A' is Includes diagram2022 · MCQ
  • Considering the above reactions, the compound 'A' and compound 'B' respectively are : Includes diagram2022 · MCQ
  • Which among the following pairs of the structures will give different products on ozonolysis? (Consider the double bonds in the structures are rigid and not delocalized.)2022 · MCQ
  • Compound 'A' undergoes following sequence of reactions to give compound 'B'. The correct structure and chirality of compound 'B' is [where Et is −C2​H5​] Includes diagram2022 · MCQ
  • In the given conversion the compound A is : Includes diagram2022 · MCQ
  • Two isomers (A) and (B) with Molar mass 184 g/mol and elemental composition C, 52.2%; H, 4.9% and Br 42.9% gave benzoic acid and p-bromobenzoic acid, respectively on oxidation with KMnO4​. Isomer 'A' is optically active and gives a pale…2022 · MCQ
  • The stable carbocation formed in the above reaction is Includes diagram2022 · MCQ