JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
Which one of the following reagents is not suitable for the elimination reaction ? 

- A/
- BNaOEt/EtOH
- C/-
- DNaI
View written solutionFree
Correct answer: D
-
Concept: Elimination in haloalkanes
Elimination of HX from an alkyl halide to form an alkene is usually favored by:
- a strong base,
- often in alcoholic medium,
- reagents such as alcoholic , , etc.
A reagent is not suitable for elimination if it does not act as a base to remove a -hydrogen.
-
Check each option
Option A:
- Aqueous mainly favors nucleophilic substitution.
- However, under suitable conditions it can still give some elimination, though it is not the best reagent.
- So it is not completely unsuitable.
Option B:
- Sodium ethoxide in ethanol is a strong base in alcoholic medium.
- This is a classic elimination reagent.
- Hence, it is suitable.
Option C: -
- Hydroalcoholic medium with base can promote elimination better than pure aqueous base.
- So this is also used for elimination.
- Hence, it is suitable.
Option D:
- provides , which is a good nucleophile but a weak base.
- It is used in substitution reactions such as Finkelstein reaction, not for elimination.
- Therefore, it is not suitable for elimination.
-
Conclusion
The reagent that is not suitable for elimination reaction is:
-
Comparison with stored correct answer
Stored correct answer =
My derived answer also =
So they agree.
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