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Haloalkanes and Haloarenes question

2014 · Shift 0 · Q9
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Haloalkanes and Haloarenes question

2014 · Shift 0 · Q9

JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
The major organic compound formed by the reaction of 1, 1, 1– trichloroethane with silver powder is:
  1. A
    2- Butyne
  2. B
    2- Butene
  3. C
    Acetylene
  4. D
    Ethene
View written solutionFree

Correct answer: A

  1. Identify the reactant

    The given compound is 1,1,1-trichloroethane.

    Its structure is: CH3−CCl3\mathrm{CH_3-CCl_3}CH3​−CCl3​

  2. Reaction with silver powder

    Silver powder causes dehalogenation/coupling of polyhalogen compounds by removing halogen as silver halide.

    For compounds of type R−CCl3\mathrm{R-CCl_3}R−CCl3​, silver removes chlorine atoms and promotes coupling of two such units.

  3. Write the overall transformation

    Two molecules of CH3−CCl3\mathrm{CH_3-CCl_3}CH3​−CCl3​ combine, with removal of chlorine as AgCl\mathrm{AgCl}AgCl, to form an alkyne: 2 CH3CCl3+6 Ag→CH3−C≡C−CH3+6 AgCl2\,\mathrm{CH_3CCl_3} + 6\,\mathrm{Ag} \rightarrow \mathrm{CH_3-C\equiv C-CH_3} + 6\,\mathrm{AgCl}2CH3​CCl3​+6Ag→CH3​−C≡C−CH3​+6AgCl

  4. Identify the product

    CH3−C≡C−CH3\mathrm{CH_3-C\equiv C-CH_3}CH3​−C≡C−CH3​ is 2-butyne.

  5. Check options

    • A: 2-Butyne →\rightarrow→ Correct
    • B: 2-Butene →\rightarrow→ No, product is an alkyne, not an alkene
    • C: Acetylene →\rightarrow→ No, carbon skeleton has 4 carbons
    • D: Ethene →\rightarrow→ No, incorrect carbon count and unsaturation
  6. Final answer

    The major organic compound formed is: 2-Butyne\boxed{\text{2-Butyne}}2-Butyne​

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