JEE MainChemistryHaloalkanes and HaloarenesMCQ+4 / −1
The major organic compound formed by the reaction of 1, 1, 1– trichloroethane with silver powder is:
- A2- Butyne
- B2- Butene
- CAcetylene
- DEthene
View written solutionFree
Correct answer: A
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Identify the reactant
The given compound is 1,1,1-trichloroethane.
Its structure is:
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Reaction with silver powder
Silver powder causes dehalogenation/coupling of polyhalogen compounds by removing halogen as silver halide.
For compounds of type , silver removes chlorine atoms and promotes coupling of two such units.
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Write the overall transformation
Two molecules of combine, with removal of chlorine as , to form an alkyne:
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Identify the product
is 2-butyne.
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Check options
- A: 2-Butyne Correct
- B: 2-Butene No, product is an alkyne, not an alkene
- C: Acetylene No, carbon skeleton has 4 carbons
- D: Ethene No, incorrect carbon count and unsaturation
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Final answer
The major organic compound formed is:
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