JEE MainChemistryElectrochemistryNumerical+4 / −1
The potential for the given half cell at is (-) (Given : )
Numerical answer
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Correct answer: 1
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Write the half-reaction and standard potential
The given half-cell is:
This is the standard hydrogen electrode, so
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Apply the Nernst equation
For the reduction reaction, at .
Here, .
-
Write the reaction quotient
For the reaction quotient is
Given:
So,
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Substitute into Nernst equation
Using ,
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Express in the required form
We need:
Since
The integer to be filled is: (taking the nearest integer)
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Comparison with stored answer
Derived answer =
Stored correct answer =
Hence, they agree.
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