JEE MainChemistryElectrochemistryNumerical+4 / −1
The mass of silver (Molar mass of ) displaced by a quantity of electricity which displaces of at S.T.P. will be g.
Numerical answer
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Correct answer: 108
- Find moles of displaced at STP
At STP, mole of gas occupies .
Given volume of oxygen:
So, moles of are:
- Relate oxygen evolved to electrons transferred
At the anode, oxygen is liberated as:
Thus, mole of corresponds to moles of electrons.
Therefore, mole of corresponds to:
So the quantity of electricity passed is 1 Faraday.
- Use this charge to find silver deposited
Silver is deposited according to:
Here, mole of electrons deposits mole of silver.
Since mole of electrons passed, moles of silver deposited:
Mass of silver:
- Final Answer
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