JEE MainChemistryElectrochemistryNumerical+4 / −1
The hydrogen electrode is dipped in a solution of at . The potential of the electrode will be .
Numerical answer
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Correct answer: 18
- Write the half-cell reaction for hydrogen electrode
For a hydrogen electrode,
- Use the Nernst equation
For the reduction reaction,
For the standard hydrogen electrode,
Assuming hydrogen gas is at standard pressure, atm. So,
This simplifies to
Since we get
Therefore,
- Substitute pH = 3
- Express in the required form
As an integer-type answer, this is taken as with negative sign for the electrode potential.
So the potential is approximately
Hence the blank should be filled with 18.
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