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Electrochemistry question

2024 · 9 Apr · Shift 1 · Q2
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  5. /2024 · 9 Apr · Shift 1 · Q2

Electrochemistry question

2024 · 9 Apr · Shift 1 · Q2

JEE MainChemistryElectrochemistryMCQ+4 / −1
The molar conductivity for electrolytes AAA and BBB are plotted against C3/2C^{3 / 2}C3/2 as shown below. Electrolytes AAA and BBB respectively are: JEE Main 2024 (Online) 9th April Morning Shift Chemistry - Electrochemistry Question 36 English
  1. A
    A - weak electrolyte \quad B - weak electrolyte
  2. B
    A - weak electrolyte \quad B - strong electrolyte
  3. C
    A - strong electrolyte \quad B - strong electrolyte
  4. D
    A - strong electrolyte \quad B - weak electrolyte
View written solutionFree

Correct answer: B

  1. Key concept: variation of molar conductivity with concentration

    Molar conductivity Λm\Lambda_mΛm​ behaves differently for strong and weak electrolytes.

    • For a strong electrolyte, Λm\Lambda_mΛm​ decreases gradually with concentration and follows approximately a linear relation of the type Λm=Λm0−KC\Lambda_m = \Lambda_m^0 - K\sqrt{C}Λm​=Λm0​−KC​ (or in a plotted transformed variable, it gives a nearly straight-line trend).

    • For a weak electrolyte, degree of ionization increases strongly on dilution, so Λm\Lambda_mΛm​ rises sharply as concentration decreases. Hence its plot is highly curved, not linear.

  2. Reading the graph qualitatively

    In the given figure, one curve corresponds to a straight-line type decrease of Λm\Lambda_mΛm​ with the concentration expression, while the other shows a curved variation.

    Therefore:

    • the straight-line plot corresponds to a strong electrolyte,
    • the curved plot corresponds to a weak electrolyte.
  3. Identification of A and B

    From the graph:

    • Electrolyte A shows the curved behavior ⇒\Rightarrow⇒ weak electrolyte.
    • Electrolyte B shows the linear behavior ⇒\Rightarrow⇒ strong electrolyte.
  4. Matching with options

    This corresponds to: A = weak electrolyte, B = strong electrolyte\text{A = weak electrolyte, B = strong electrolyte}A = weak electrolyte, B = strong electrolyte

    So the correct option is B.

  5. Comparison with stored answer

    Stored correct answer = B.

    Our derived answer also = B.

    Hence, they agree.

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