JEE MainChemistryElectrochemistryMCQ+4 / −1
Molar ionic conductivities of divalent cation and anion are and respectively. The molar conductivity of solution of an electrolyte with the above cation and anion will be:
- A
- B
- C
- D
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Correct answer: D
- Use Kohlrausch’s law of independent migration of ions
For an electrolyte, the molar conductivity at infinite dilution is the sum of the molar ionic conductivities of the ions, each multiplied by its stoichiometric coefficient:
- Identify the electrolyte type
The cation is divalent and the anion is also divalent.
So the electrolyte formed is of type:
Thus, the stoichiometric coefficients are:
- Substitute the given ionic conductivities
Given:
Hence,
- Match with the options
So the correct option is D.
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