- ASilver and gold in equal mass proportion
- BSilver and gold in proportion to their atomic weights
- COnly gold
- DOnly silver
View written solutionFree
Correct answer: C
- Identify the ions present and their reduction potentials
The solution contains:
Given standard reduction potentials:
Since for is higher, is reduced more easily than .
- Find initial moles of each ion
Volume of solution:
Concentration of each salt =
So moles of each ion initially:
- Calculate total charge passed
Current passed: Time:
Hence charge passed:
Moles of electrons supplied:
- Compare required electrons with available electrons
Both reductions are one-electron processes:
To reduce all present, required electrons would be:
But available electrons are only:
So the total charge is insufficient to reduce all , and since has the higher reduction potential, it will be discharged preferentially.
Thus only gets reduced in the given time.
- Check whether silver can start depositing
As long as is present, cathode potential required for gold deposition is more favorable than that for silver. Since the available charge cannot even exhaust all the gold ions, silver deposition does not begin.
Hence deposited metal is only gold.
- Correct option
- Comparison with stored answer
Stored correct answer: C
My derived answer: C
So, they agree.
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