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D and F Block Elements question

2024 · 29 Jan · Shift 2 · Q8
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D and F Block Elements question

2024 · 29 Jan · Shift 2 · Q8

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which of the following statements are correct about Zn,Cd\mathrm{Zn}, \mathrm{Cd}Zn,Cd and Hg\mathrm{Hg}Hg? A. They exhibit high enthalpy of atomization as the d-subshell is full. B. Zn\mathrm{Zn}Zn and Cd\mathrm{Cd}Cd do not show variable oxidation state while Hg\mathrm{Hg}Hg shows +I+\mathrm{I}+I and +II+\mathrm{II}+II. C. Compounds of Zn,Cd\mathrm{Zn}, \mathrm{Cd}Zn,Cd and Hg\mathrm{Hg}Hg are paramagnetic in nature. D. Zn,Cd\mathrm{Zn}, \mathrm{Cd}Zn,Cd and Hg\mathrm{Hg}Hg are called soft metals. Choose the most appropriate from the options given below:
  1. A
    C, D only
  2. B
    B, C only
  3. C
    A, D only
  4. D
    B, D only
View written solutionFree

Correct answer: D

  1. Electronic configuration and general nature

    The elements are:

    • Zn:[Ar]3d104s2\mathrm{Zn}: [Ar]3d^{10}4s^2Zn:[Ar]3d104s2
    • Cd:[Kr]4d105s2\mathrm{Cd}: [Kr]4d^{10}5s^2Cd:[Kr]4d105s2
    • Hg:[Xe]4f145d106s2\mathrm{Hg}: [Xe]4f^{14}5d^{10}6s^2Hg:[Xe]4f145d106s2

    Since the ddd-subshell is completely filled in their common states, these elements behave somewhat differently from typical transition metals.

  2. Check statement A

    A. They exhibit high enthalpy of atomization as the ddd-subshell is full.

    This is incorrect. A completely filled d10d^{10}d10 configuration means weaker metallic bonding compared with many transition metals having partially filled ddd-orbitals. Hence Zn,Cd,Hg\mathrm{Zn}, \mathrm{Cd}, \mathrm{Hg}Zn,Cd,Hg do not have high enthalpy of atomization for this reason.

    So, A is false.

  3. Check statement B

    B. Zn\mathrm{Zn}Zn and Cd\mathrm{Cd}Cd do not show variable oxidation state while Hg\mathrm{Hg}Hg shows +I+\mathrm{I}+I and +II+\mathrm{II}+II.

    This is correct:

    • Zn\mathrm{Zn}Zn commonly shows only +2+2+2
    • Cd\mathrm{Cd}Cd commonly shows only +2+2+2
    • Hg\mathrm{Hg}Hg shows both +1+1+1 and +2+2+2

    Note: In the +1+1+1 state, mercury exists as the dimeric ion Hg22+\mathrm{Hg_2^{2+}}Hg22+​.

    So, B is true.

  4. Check statement C

    C. Compounds of Zn,Cd\mathrm{Zn}, \mathrm{Cd}Zn,Cd and Hg\mathrm{Hg}Hg are paramagnetic in nature.

    This is incorrect. Their common ions are:

    • Zn2+:3d10\mathrm{Zn^{2+}}: 3d^{10}Zn2+:3d10
    • Cd2+:4d10\mathrm{Cd^{2+}}: 4d^{10}Cd2+:4d10
    • Hg2+:5d10\mathrm{Hg^{2+}}: 5d^{10}Hg2+:5d10

    All are completely filled d10d^{10}d10 systems, so they are generally diamagnetic, not paramagnetic.

    So, C is false.

  5. Check statement D

    D. Zn,Cd\mathrm{Zn}, \mathrm{Cd}Zn,Cd and Hg\mathrm{Hg}Hg are called soft metals.

    This is correct. These are relatively soft metals with low melting/boiling characteristics compared with many transition metals; mercury is liquid at room temperature.

    So, D is true.

  6. Final selection

    Correct statements are: B and DB \text{ and } DB and D

    Therefore, the correct option is: D\boxed{\text{D}}D​

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