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D and F Block Elements question

2024 · 29 Jan · Shift 2 · Q3
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D and F Block Elements question

2024 · 29 Jan · Shift 2 · Q3

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which of the following acts as a strong reducing agent? (Atomic number: Ce=58,Eu=63,Gd=64,Lu=71\mathrm{Ce}=58, \mathrm{Eu}=63, \mathrm{Gd}=64, \mathrm{Lu}=71Ce=58,Eu=63,Gd=64,Lu=71)
  1. A
    Eu2+\mathrm{Eu}^{2+}Eu2+
  2. B
    Gd3+\mathrm{Gd}^{3+}Gd3+
  3. C
    Lu3+\mathrm{Lu}^{3+}Lu3+
  4. D
    Ce4+\mathrm{Ce}^{4+}Ce4+
View written solutionFree

Correct answer: A

  1. Identify what “strong reducing agent” means

A strong reducing agent is a species that readily loses electrons and gets oxidized.

So we must find the species that is most easily oxidized to a more stable oxidation state.


  1. Use the special stability of lanthanide electronic configurations

Among lanthanides, certain oxidation states are especially stable due to electronic configuration:

  • Ce4+\mathrm{Ce}^{4+}Ce4+ is stable because Ce has configuration: Ce:[Xe]4f15d16s2\mathrm{Ce}: [Xe]4f^15d^16s^2Ce:[Xe]4f15d16s2 and Ce4+:[Xe]\mathrm{Ce}^{4+} : [Xe]Ce4+:[Xe] which is a noble-gas configuration.

  • Eu2+\mathrm{Eu}^{2+}Eu2+ is stable because: Eu:[Xe]4f76s2\mathrm{Eu}: [Xe]4f^76s^2Eu:[Xe]4f76s2 so Eu2+:[Xe]4f7\mathrm{Eu}^{2+} : [Xe]4f^7Eu2+:[Xe]4f7 which is a half-filled 4f4f4f shell, especially stable.

  • Gd3+\mathrm{Gd}^{3+}Gd3+ is stable because: Gd:[Xe]4f75d16s2\mathrm{Gd}: [Xe]4f^75d^16s^2Gd:[Xe]4f75d16s2 so Gd3+:[Xe]4f7\mathrm{Gd}^{3+} : [Xe]4f^7Gd3+:[Xe]4f7 again half-filled and very stable.

  • Lu3+\mathrm{Lu}^{3+}Lu3+ is stable because: Lu:[Xe]4f145d16s2\mathrm{Lu}: [Xe]4f^{14}5d^16s^2Lu:[Xe]4f145d16s2 so Lu3+:[Xe]4f14\mathrm{Lu}^{3+} : [Xe]4f^{14}Lu3+:[Xe]4f14 which is a completely filled 4f4f4f shell.


  1. Check which species can act as a reducing agent

A reducing agent gets oxidized.

Option A: Eu2+\mathrm{Eu}^{2+}Eu2+

It can be oxidized to: Eu2+→Eu3++e−\mathrm{Eu}^{2+} \rightarrow \mathrm{Eu}^{3+} + e^-Eu2+→Eu3++e− Since lanthanides generally prefer the +3+3+3 oxidation state, Eu2+\mathrm{Eu}^{2+}Eu2+ readily gives up one electron. Thus Eu2+\mathrm{Eu}^{2+}Eu2+ acts as a strong reducing agent.

Option B: Gd3+\mathrm{Gd}^{3+}Gd3+

Gd3+\mathrm{Gd}^{3+}Gd3+ is already a highly stable common oxidation state. It is not easily oxidized further, so it is not a strong reducing agent.

Option C: Lu3+\mathrm{Lu}^{3+}Lu3+

Lu3+\mathrm{Lu}^{3+}Lu3+ is also a very stable state with 4f144f^{14}4f14. It does not readily lose electrons further, so it is not a strong reducing agent.

Option D: Ce4+\mathrm{Ce}^{4+}Ce4+

Ce4+\mathrm{Ce}^{4+}Ce4+ tends to gain an electron to become Ce3+\mathrm{Ce}^{3+}Ce3+, so it behaves as an oxidizing agent, not a reducing agent.


  1. Conclusion

The species that acts as a strong reducing agent is: Eu2+\boxed{\mathrm{Eu}^{2+}}Eu2+​

So the correct option is A.

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