- A
- B
- C
- D
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Correct answer: A
- Identify what “strong reducing agent” means
A strong reducing agent is a species that readily loses electrons and gets oxidized.
So we must find the species that is most easily oxidized to a more stable oxidation state.
- Use the special stability of lanthanide electronic configurations
Among lanthanides, certain oxidation states are especially stable due to electronic configuration:
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is stable because Ce has configuration: and which is a noble-gas configuration.
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is stable because: so which is a half-filled shell, especially stable.
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is stable because: so again half-filled and very stable.
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is stable because: so which is a completely filled shell.
- Check which species can act as a reducing agent
A reducing agent gets oxidized.
Option A:
It can be oxidized to: Since lanthanides generally prefer the oxidation state, readily gives up one electron. Thus acts as a strong reducing agent.
Option B:
is already a highly stable common oxidation state. It is not easily oxidized further, so it is not a strong reducing agent.
Option C:
is also a very stable state with . It does not readily lose electrons further, so it is not a strong reducing agent.
Option D:
tends to gain an electron to become , so it behaves as an oxidizing agent, not a reducing agent.
- Conclusion
The species that acts as a strong reducing agent is:
So the correct option is A.
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