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D and F Block Elements question

2023 · 30 Jan · Shift 2 · Q1
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D and F Block Elements question

2023 · 30 Jan · Shift 2 · Q1

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Formulae for Nessler's reagent is :
  1. A
    KHgI3\mathrm{KHgI}_3KHgI3​
  2. B
    HgI2\mathrm{HgI}_2HgI2​
  3. C
    KHg2I2\mathrm{KHg}_2 \mathrm{I}_2KHg2​I2​
  4. D
    K2HgI4\mathrm{K}_2 \mathrm{HgI}_4K2​HgI4​
View written solutionFree

Correct answer: D

  1. Recall what Nessler's reagent is

    Nessler's reagent is an alkaline solution of potassium tetraiodomercurate(II).

  2. Write the complex ion present

    The tetraiodomercurate(II) ion is: [HgI4]2−[\mathrm{HgI}_4]^{2-}[HgI4​]2−

  3. Balance the charge with potassium ions

    Since the complex ion has charge −2-2−2, it requires 222 potassium ions: K2[HgI4]\mathrm{K}_2[\mathrm{HgI}_4]K2​[HgI4​]

    This is written as: K2HgI4\mathrm{K}_2\mathrm{HgI}_4K2​HgI4​

  4. Check the options

    • A: KHgI3\mathrm{KHgI}_3KHgI3​ — not the standard formula of Nessler's reagent.
    • B: HgI2\mathrm{HgI}_2HgI2​ — this is mercuric iodide, not Nessler's reagent.
    • C: KHg2I2\mathrm{KHg}_2\mathrm{I}_2KHg2​I2​ — incorrect formula.
    • D: K2HgI4\mathrm{K}_2\mathrm{HgI}_4K2​HgI4​ — correct.
  5. Final answer

    Nessler's reagent is: K2HgI4\boxed{\mathrm{K}_2\mathrm{HgI}_4}K2​HgI4​​

So, the correct option is D.

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