JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Which one of the following statements is correct?
- AFrom a mixed precipitate of AgCl and AgI, ammonia solution dissolves only AgCl
- BFerric ions give a deep green precipitate on adding potassium ferrocyanide solution
- COn boiling a solution having , and ions we get a precipitate of .
- DManganese salts give a violet borax bead test in the reducing flame
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Correct answer: A
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We evaluate each option using standard qualitative inorganic chemistry facts.
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Option A: From a mixed precipitate of and , ammonia solution dissolves only .
- dissolves in aqueous ammonia due to complex formation:
- does not dissolve in ammonia because it is much less soluble and does not form the complex sufficiently.
Therefore, A is correct.
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Option B: Ferric ions give a deep green precipitate on adding potassium ferrocyanide solution.
- with potassium ferrocyanide gives Prussian blue coloration/precipitate, not deep green.
- The product is ferric ferrocyanide.
Therefore, B is incorrect.
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Option C: On boiling a solution having , and ions we get a precipitate of .
- On boiling bicarbonate solution, bicarbonate decomposes:
- Then forms insoluble calcium carbonate:
- Potassium salts remain soluble; no such precipitate is formed.
Therefore, C is incorrect.
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Option D: Manganese salts give a violet borax bead test in the reducing flame.
- Manganese gives an amethyst/violet bead in oxidizing flame.
- In reducing flame, the color changes and is not violet as stated.
Therefore, D is incorrect.
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Hence, the only correct statement is:
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