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D and F Block Elements question

2004 · Shift 0 · Q47
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D and F Block Elements question

2004 · Shift 0 · Q47

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Cerium (Z = 58) is an important member of the lanthanoids. Which of the following statements about cerium is incorrect?
  1. A
    The common oxidation states of cerium are +3 and +4
  2. B
    Cerium (IV) acts as an oxidizing agent
  3. C
    The +4 oxidation state of cerium is not known in solutions
  4. D
    The +3 oxidation state of cerium is more stable than the +4 oxidation state
View written solutionFree

Correct answer: C

  1. Electronic configuration of cerium
    Cerium, Z=58Z=58Z=58, has electronic configuration close to: [Xe]4f15d16s2[Xe]4f^1 5d^1 6s^2[Xe]4f15d16s2 or often written effectively as [Xe]4f15d16s2[Xe]4f^1 5d^1 6s^2[Xe]4f15d16s2.

Because lanthanoids commonly lose the two 6s6s6s electrons and sometimes one more electron, the +3+3+3 oxidation state is the most common. Cerium is special because it can also form a stable +4+4+4 oxidation state.

  1. Check option A: "The common oxidation states of cerium are +3+3+3 and +4+4+4"
    This is true. Cerium commonly shows both +3+3+3 and +4+4+4 oxidation states.

  2. Check option B: "Cerium (IV) acts as an oxidizing agent"
    This is true. Since Ce4+Ce^{4+}Ce4+ readily gets reduced to Ce3+Ce^{3+}Ce3+, it behaves as an oxidizing agent.

  3. Check option C: "The +4+4+4 oxidation state of cerium is not known in solutions"
    This is false. Cerium(IV) does exist in solution, for example in acidic medium, and Ce4+/Ce3+Ce^{4+}/Ce^{3+}Ce4+/Ce3+ is a well-known redox couple used in volumetric analysis. Therefore this statement is incorrect.

  4. Check option D: "The +3+3+3 oxidation state of cerium is more stable than the +4+4+4 oxidation state"
    This is generally true for lanthanoids, and for cerium the +3+3+3 state is common and stable, although +4+4+4 is also important due to extra stability in compounds like CeO2CeO_2CeO2​.

  5. Conclusion
    The incorrect statement is: C\boxed{\text{C}}C​

  6. Comparison with stored answer
    Stored correct answer is C, which matches the derived answer.

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