- AThe common oxidation states of cerium are +3 and +4
- BCerium (IV) acts as an oxidizing agent
- CThe +4 oxidation state of cerium is not known in solutions
- DThe +3 oxidation state of cerium is more stable than the +4 oxidation state
View written solutionFree
Correct answer: C
- Electronic configuration of cerium
Cerium, , has electronic configuration close to: or often written effectively as .
Because lanthanoids commonly lose the two electrons and sometimes one more electron, the oxidation state is the most common. Cerium is special because it can also form a stable oxidation state.
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Check option A: "The common oxidation states of cerium are and "
This is true. Cerium commonly shows both and oxidation states. -
Check option B: "Cerium (IV) acts as an oxidizing agent"
This is true. Since readily gets reduced to , it behaves as an oxidizing agent. -
Check option C: "The oxidation state of cerium is not known in solutions"
This is false. Cerium(IV) does exist in solution, for example in acidic medium, and is a well-known redox couple used in volumetric analysis. Therefore this statement is incorrect. -
Check option D: "The oxidation state of cerium is more stable than the oxidation state"
This is generally true for lanthanoids, and for cerium the state is common and stable, although is also important due to extra stability in compounds like . -
Conclusion
The incorrect statement is: -
Comparison with stored answer
Stored correct answer is C, which matches the derived answer.
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