JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Excess of reacts with solution and then solution is added to it. Which of the statements is incorrect for this reaction?
- Ais reduced
- BEvolved is reduced
- Cis oxidized
- Dis formed
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Correct answer: D
- Reaction of excess with
Copper(II) ions oxidize iodide ions to iodine, while themselves getting reduced to copper(I), which precipitates as cuprous iodide.
The reaction is:
So in this step:
- : reduction
- : oxidation
- The precipitate formed is (sometimes written as as dimeric form)
Thus, statement A: " is reduced" is acceptable, because ultimately gets reduced to cuprous iodide.
- Addition of to the liberated iodine
Sodium thiosulfate reacts with iodine as:
Here:
- : reduction
- : oxidation
So:
- Statement B " is reduced" is correct.
- Statement C " is oxidized" is correct.
- Check statement about
In the reaction of with excess , is not formed as a stable product. Instead, oxidizes iodide and itself gets reduced to .
So statement D " is formed" is incorrect.
- Option-wise conclusion
- A: Correct
- B: Correct
- C: Correct
- D: Incorrect
Therefore, the incorrect statement is:
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