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D and F Block Elements question

2004 · Shift 0 · Q46
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D and F Block Elements question

2004 · Shift 0 · Q46

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Excess of KIKIKI reacts with CuSO4CuSO_4CuSO4​ solution and then Na2S2O3Na_2S_2O_3Na2​S2​O3​ solution is added to it. Which of the statements is incorrect for this reaction?
  1. A
    Cu2I2Cu_2I_2Cu2​I2​ is reduced
  2. B
    Evolved I2I_2I2​ is reduced
  3. C
    Na2S2O3Na_2S_2O_3Na2​S2​O3​ is oxidized
  4. D
    CuI2CuI_2CuI2​ is formed
View written solutionFree

Correct answer: D

  1. Reaction of excess KIKIKI with CuSO4CuSO_4CuSO4​

Copper(II) ions oxidize iodide ions to iodine, while themselves getting reduced to copper(I), which precipitates as cuprous iodide.

The reaction is:

2CuSO4+4KI→2CuI↓+I2+2K2SO42CuSO_4 + 4KI \rightarrow 2CuI\downarrow + I_2 + 2K_2SO_42CuSO4​+4KI→2CuI↓+I2​+2K2​SO4​

So in this step:

  • Cu2+→Cu+Cu^{2+} \to Cu^+Cu2+→Cu+ : reduction
  • I−→I2I^- \to I_2I−→I2​ : oxidation
  • The precipitate formed is CuICuICuI (sometimes written as Cu2I2Cu_2I_2Cu2​I2​ as dimeric form)

Thus, statement A: "Cu2I2Cu_2I_2Cu2​I2​ is reduced" is acceptable, because Cu2+Cu^{2+}Cu2+ ultimately gets reduced to cuprous iodide.


  1. Addition of Na2S2O3Na_2S_2O_3Na2​S2​O3​ to the liberated iodine

Sodium thiosulfate reacts with iodine as:

I2+2S2O32−→2I−+S4O62−I_2 + 2S_2O_3^{2-} \rightarrow 2I^- + S_4O_6^{2-}I2​+2S2​O32−​→2I−+S4​O62−​

Here:

  • I2→I−I_2 \to I^-I2​→I− : reduction
  • S2O32−→S4O62−S_2O_3^{2-} \to S_4O_6^{2-}S2​O32−​→S4​O62−​ : oxidation

So:

  • Statement B "Evolved I2Evolved\, I_2EvolvedI2​ is reduced" is correct.
  • Statement C "Na2S2O3Na_2S_2O_3Na2​S2​O3​ is oxidized" is correct.

  1. Check statement about CuI2CuI_2CuI2​

In the reaction of CuSO4CuSO_4CuSO4​ with excess KIKIKI, CuI2CuI_2CuI2​ is not formed as a stable product. Instead, Cu2+Cu^{2+}Cu2+ oxidizes iodide and itself gets reduced to CuICuICuI.

So statement D "CuI2CuI_2CuI2​ is formed" is incorrect.


  1. Option-wise conclusion
  • A: Correct
  • B: Correct
  • C: Correct
  • D: Incorrect

Therefore, the incorrect statement is:

D\boxed{D}D​

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