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D and F Block Elements question

2003 · Shift 0 · Q45
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D and F Block Elements question

2003 · Shift 0 · Q45

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
What would happen when a solution of potassium chromate is treated with an excess of dilute nitric acid?
  1. A
    Cr2O72−Cr_2O^{2-}_7Cr2​O72−​ and H2OH_2OH2​O are formed
  2. B
    CrO42−CrO^{2-}_4CrO42−​ is reduced to +3 state of Cr
  3. C
    CrO42−CrO^{2-}_4CrO42−​ is oxidized to +7 state of Cr
  4. D
    Cr3+Cr^{3+}Cr3+ and Cr2O72−Cr_2O^{2-}_7Cr2​O72−​ are formed
View written solutionFree

Correct answer: A

  1. Identify the species present

Potassium chromate contains the chromate ion: CrO42−\mathrm{CrO_4^{2-}}CrO42−​ In this ion, chromium is in the +6+6+6 oxidation state.

  1. Effect of adding dilute nitric acid

On acidification, chromate ions convert into dichromate ions according to the equilibrium: 2CrO42−+2H+⇌Cr2O72−+H2O2\mathrm{CrO_4^{2-}} + 2\mathrm{H^+} \rightleftharpoons \mathrm{Cr_2O_7^{2-}} + \mathrm{H_2O}2CrO42−​+2H+⇌Cr2​O72−​+H2​O

Since excess dilute nitric acid is added, the equilibrium shifts to the right, producing dichromate ion and water.

  1. Check oxidation state change
  • In CrO42−\mathrm{CrO_4^{2-}}CrO42−​, Cr is +6+6+6
  • In Cr2O72−\mathrm{Cr_2O_7^{2-}}Cr2​O72−​, each Cr is also +6+6+6

So this is not a redox reaction. It is only an acid-base equilibrium shift.

  1. Evaluate the options
  • A: Cr2O72−\mathrm{Cr_2O_7^{2-}}Cr2​O72−​ and H2O\mathrm{H_2O}H2​O are formed
    ✅ Correct, from 2CrO42−+2H+→Cr2O72−+H2O2\mathrm{CrO_4^{2-}} + 2\mathrm{H^+} \rightarrow \mathrm{Cr_2O_7^{2-}} + \mathrm{H_2O}2CrO42−​+2H+→Cr2​O72−​+H2​O

  • B: CrO42−\mathrm{CrO_4^{2-}}CrO42−​ is reduced to +3+3+3 state of Cr
    ❌ Incorrect, nitric acid here only acidifies; no reduction to Cr3+\mathrm{Cr^{3+}}Cr3+ occurs.

  • C: CrO42−\mathrm{CrO_4^{2-}}CrO42−​ is oxidized to +7+7+7 state of Cr
    ❌ Incorrect, chromium remains at +6+6+6.

  • D: Cr3+\mathrm{Cr^{3+}}Cr3+ and Cr2O72−\mathrm{Cr_2O_7^{2-}}Cr2​O72−​ are formed
    ❌ Incorrect, Cr3+\mathrm{Cr^{3+}}Cr3+ is not produced.

  1. Final answer

Therefore, the correct option is: A\boxed{A}A​

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