JEE MainChemistryD and F Block ElementsMCQ+4 / −1
What would happen when a solution of potassium chromate is treated with an excess of dilute nitric acid?
- Aand are formed
- Bis reduced to +3 state of Cr
- Cis oxidized to +7 state of Cr
- Dand are formed
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Correct answer: A
- Identify the species present
Potassium chromate contains the chromate ion: In this ion, chromium is in the oxidation state.
- Effect of adding dilute nitric acid
On acidification, chromate ions convert into dichromate ions according to the equilibrium:
Since excess dilute nitric acid is added, the equilibrium shifts to the right, producing dichromate ion and water.
- Check oxidation state change
- In , Cr is
- In , each Cr is also
So this is not a redox reaction. It is only an acid-base equilibrium shift.
- Evaluate the options
-
A: and are formed
✅ Correct, from -
B: is reduced to state of Cr
❌ Incorrect, nitric acid here only acidifies; no reduction to occurs. -
C: is oxidized to state of Cr
❌ Incorrect, chromium remains at . -
D: and are formed
❌ Incorrect, is not produced.
- Final answer
Therefore, the correct option is:
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