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Coordination Compounds question

2025 · 24 Jan · Shift 1 · Q12

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JEE Main
Chemistry
Coordination Compounds
2025 · 24 Jan · Shift 1 · Q12

Coordination Compounds question

2025 · 24 Jan · Shift 1 · Q12

JEE MainChemistryCoordination CompoundsMCQ+4 / −1

One mole of the octahedral complex compound

\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}_3

gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with excess of

\mathrm{AgNO}_3

solution to yield two moles of

\mathrm{AgCl}_{(\mathrm{s})}

. The structure of the complex is:

A
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$
B
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\right] \cdot \mathrm{Cl}_2 \cdot \mathrm{NH}_3$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right] \cdot 2 \mathrm{NH}_3$
D
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \cdot \mathrm{Cl} \cdot \mathrm{NH}_3$

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