JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The spin only magnetic moment ( ) value (B.M.) of the compound with strongest oxidising power among and VO is B.M. (Nearest integer).
Numerical answer
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Correct answer: 5
- Find oxidation states of the metal ions
-
In : So manganese is .
-
In : So titanium is .
-
In : So vanadium is .
- Determine which compound has the strongest oxidising power
An oxidising agent gets reduced, so the species in the higher oxidation state generally shows greater oxidising power.
Here the metal oxidation states are:
Thus, among these, containing has the strongest oxidising power.
- Find electronic configuration of
Atomic number of Mn = 25.
Neutral Mn:
For , remove two electrons and one electron:
So number of unpaired electrons, .
- Calculate spin-only magnetic moment
Formula:
Substitute :
Nearest integer:
- Comparison with stored answer
Derived answer =
Stored correct answer =
Hence, they agree.
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