Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Coordination Compounds question

2025 · 28 Jan · Shift 2 · Q21
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Coordination Compounds
  5. /2025 · 28 Jan · Shift 2 · Q21

Coordination Compounds question

2025 · 28 Jan · Shift 2 · Q21

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The spin only magnetic moment ( μ\muμ) value (B.M.) of the compound with strongest oxidising power among Mn2O3,TiO\mathrm{Mn}_2 \mathrm{O}_3, \mathrm{TiO}Mn2​O3​,TiO and VO is ‾\underline{\hspace{2cm}}​ B.M. (Nearest integer).
Numerical answer
View written solutionFree

Correct answer: 5

  1. Find oxidation states of the metal ions
  • In Mn2O3\mathrm{Mn_2O_3}Mn2​O3​: 2x+3(−2)=0⇒2x−6=0⇒x=+32x + 3(-2)=0 \Rightarrow 2x-6=0 \Rightarrow x=+32x+3(−2)=0⇒2x−6=0⇒x=+3 So manganese is Mn3+\mathrm{Mn^{3+}}Mn3+.

  • In TiO\mathrm{TiO}TiO: x+(−2)=0⇒x=+2x+(-2)=0 \Rightarrow x=+2x+(−2)=0⇒x=+2 So titanium is Ti2+\mathrm{Ti^{2+}}Ti2+.

  • In VO\mathrm{VO}VO: x+(−2)=0⇒x=+2x+(-2)=0 \Rightarrow x=+2x+(−2)=0⇒x=+2 So vanadium is V2+\mathrm{V^{2+}}V2+.

  1. Determine which compound has the strongest oxidising power

An oxidising agent gets reduced, so the species in the higher oxidation state generally shows greater oxidising power.

Here the metal oxidation states are:

  • Mn3+\mathrm{Mn^{3+}}Mn3+
  • Ti2+\mathrm{Ti^{2+}}Ti2+
  • V2+\mathrm{V^{2+}}V2+

Thus, among these, Mn2O3\mathrm{Mn_2O_3}Mn2​O3​ containing Mn3+\mathrm{Mn^{3+}}Mn3+ has the strongest oxidising power.

  1. Find electronic configuration of Mn3+\mathrm{Mn^{3+}}Mn3+

Atomic number of Mn = 25.

Neutral Mn: [Ar] 3d54s2[\mathrm{Ar}]\,3d^5 4s^2[Ar]3d54s2

For Mn3+\mathrm{Mn^{3+}}Mn3+, remove two 4s4s4s electrons and one 3d3d3d electron: Mn3+:[Ar] 3d4\mathrm{Mn^{3+}}:[\mathrm{Ar}]\,3d^4Mn3+:[Ar]3d4

So number of unpaired electrons, n=4n=4n=4.

  1. Calculate spin-only magnetic moment

Formula: μ=n(n+2)  B.M.\mu = \sqrt{n(n+2)}\;\text{B.M.}μ=n(n+2)​B.M.

Substitute n=4n=4n=4: μ=4(4+2)=24≈4.90  B.M.\mu = \sqrt{4(4+2)}=\sqrt{24} \approx 4.90\;\text{B.M.}μ=4(4+2)​=24​≈4.90B.M.

Nearest integer: 5\boxed{5}5​

  1. Comparison with stored answer

Derived answer = 555

Stored correct answer = 555

Hence, they agree.

PreviousNext

More from Coordination Compounds

  • Total number of molecules/species from following which will be paramagnetic is ​. O2​,O2+​,O2−​,NO,NO2​,CO,K2​[NiCl4​],[Co(NH3​)6​]Cl3​, K2​[Ni(CN)4​]…2025 · Numerical
  • Match List - I with List - II. Choose the correct answer from the options given below: Includes table2025 · MCQ
  • Match List - I with List - II. Choose the correct answer from the options given below : Includes table2025 · MCQ
  • The correct increasing order of stability of the complexes based on Δ0​ value is : I. [Mn(CN)6​]3− II. [Co(CN)6​]4− III. [Fe(CN)6​]4− IV. [Fe(CN)6​]3−2025 · MCQ
  • The calculated spin-only magnetic moments of K3​[Fe(OH)6​] and K4​[Fe(OH)6​] respectively are :2025 · MCQ
  • Consider the following low-spin complexes K3​[Co(NO2​)6​],K4​[Fe(CN)6​],K3​[Fe(CN)6​],Cu2​[Fe(CN)6​] and Zn2​[Fe(CN)6​]…2025 · Numerical
  • Identify the homoleptic complexes with odd number of d electrons in the central metal : (A) [FeO4​]2−(B) [Fe(CN)6​]3−(C) $\left[\mathrm{Fe}(\mathrm{CN})_5…2025 · MCQ
  • Given below are two statements : Statement (I) : A solution of [Ni(H2​O)6​]2+ is green in colour. Statement (II) : A solution of [Ni(CN)4​]2− is…2024 · MCQ