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- Identify the metal with least metallic radius
Among the given 3d-series elements: metallic radius generally decreases across a period from left to right due to increasing effective nuclear charge.
Hence, among these, the least metallic radius is for:
So the ion is:
- Find the oxidation state of Zn
Let oxidation state of Zn be .
Each oxygen has oxidation number .
So,
Thus, Zn is in oxidation state:
- Find the electronic configuration of Zn and
Atomic number of Zn = 30
Ground-state electronic configuration of Zn:
For , remove 2 electrons from and 4 electrons from :
- Determine number of unpaired electrons in
is a tetrahedral oxoanion. For a tetrahedral field, splitting is small and generally high spin.
So for tetrahedral configuration, the electron arrangement has 4 unpaired electrons.
Thus,
- Calculate spin-only magnetic moment
Spin-only magnetic moment is:
Substitute :
Since the question is of integer type, the required value is:
- Compare with stored correct answer
Stored correct answer =
My derived answer is , so I do not agree with the stored answer.
The likely reason is that the intended species may have been assumed differently, but based on the given wording, the metal with least metallic radius is Zn, leading to and a nonzero magnetic moment.
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