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Coordination Compounds question

2024 · 8 Apr · Shift 1 · Q29
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Coordination Compounds question

2024 · 8 Apr · Shift 1 · Q29

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The 'spin only' magnetic moment value of MO42−\mathrm{MO}_4{ }^{2-}MO4​2− is ‾\underline{\hspace{2cm}}​ BM. (Where M is a metal having least metallic radii. among Sc,Ti,V,Cr,Mn\mathrm{Sc}, \mathrm{Ti}, \mathrm{V}, \mathrm{Cr}, \mathrm{Mn}Sc,Ti,V,Cr,Mn and Zn\mathrm{Zn}Zn ). (Given atomic number: Sc=21,Ti=22, V=23,Cr=24,Mn=25\mathrm{Sc}=21, \mathrm{Ti}=22, \mathrm{~V}=23, \mathrm{Cr}=24, \mathrm{Mn}=25Sc=21,Ti=22, V=23,Cr=24,Mn=25 and Zn=30\mathrm{Zn}=30Zn=30)
Numerical answer
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Correct answer: 0

  1. Identify the metal with least metallic radius

Among the given 3d-series elements: Sc, Ti, V, Cr, Mn, Zn\mathrm{Sc},\ Ti,\ V,\ Cr,\ Mn,\ ZnSc, Ti, V, Cr, Mn, Zn metallic radius generally decreases across a period from left to right due to increasing effective nuclear charge.

Hence, among these, the least metallic radius is for: Zn\boxed{\mathrm{Zn}}Zn​

So the ion is: ZnO42−\mathrm{ZnO_4^{2-}}ZnO42−​


  1. Find the oxidation state of Zn

Let oxidation state of Zn be xxx.

Each oxygen has oxidation number −2-2−2.

So, x+4(−2)=−2x + 4(-2) = -2x+4(−2)=−2 x−8=−2x - 8 = -2x−8=−2 x=+6x = +6x=+6

Thus, Zn is in oxidation state: +6\boxed{+6}+6​


  1. Find the electronic configuration of Zn and Zn6+\mathrm{Zn^{6+}}Zn6+

Atomic number of Zn = 30

Ground-state electronic configuration of Zn: Zn:[Ar]3d104s2\mathrm{Zn} : [Ar]3d^{10}4s^2Zn:[Ar]3d104s2

For Zn6+\mathrm{Zn^{6+}}Zn6+, remove 2 electrons from 4s4s4s and 4 electrons from 3d3d3d: Zn6+:[Ar]3d6\mathrm{Zn^{6+}} : [Ar]3d^6Zn6+:[Ar]3d6


  1. Determine number of unpaired electrons in ZnO42−\mathrm{ZnO_4^{2-}}ZnO42−​

MO42−\mathrm{MO_4^{2-}}MO42−​ is a tetrahedral oxoanion. For a tetrahedral field, splitting is small and generally high spin.

So for d6d^6d6 tetrahedral configuration, the electron arrangement has 4 unpaired electrons.

Thus, n=4n = 4n=4


  1. Calculate spin-only magnetic moment

Spin-only magnetic moment is: μ=n(n+2) BM\mu = \sqrt{n(n+2)}\ \text{BM}μ=n(n+2)​ BM

Substitute n=4n=4n=4: μ=4(4+2)=24\mu = \sqrt{4(4+2)} = \sqrt{24}μ=4(4+2)​=24​ μ≈4.90 BM\mu \approx 4.90\ \text{BM}μ≈4.90 BM

Since the question is of integer type, the required value is: 5\boxed{5}5​


  1. Compare with stored correct answer

Stored correct answer = 000

My derived answer is 555, so I do not agree with the stored answer.

The likely reason is that the intended species may have been assumed differently, but based on the given wording, the metal with least metallic radius is Zn, leading to ZnO42−\mathrm{ZnO_4^{2-}}ZnO42−​ and a nonzero magnetic moment.

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