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Coordination Compounds question

2024 · 9 Apr · Shift 1 · Q15
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Coordination Compounds question

2024 · 9 Apr · Shift 1 · Q15

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): The total number of geometrical isomers shown by [Co(en)2Cl2]+[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2]^{+}[Co(en)2​Cl2​]+ complex ion is three. Reason (R): [Co(en)2Cl2]+[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2]^{+}[Co(en)2​Cl2​]+ complex ion has an octahedral geometry. In the light of the above statements, choose the most appropriate answer from the options given below :
  1. A
    (A) is correct but (R) is not correct
  2. B
    (A) is not correct but (R) is correct
  3. C
    Both (A) and (R) are correct but (R) is not the correct explanation of (A)
  4. D
    Both (A) and (R) are correct and (R) is the correct explanation of (A)
View written solutionFree

Correct answer: B

  1. Identify the complex and its geometry

The complex ion is [Co(en)2Cl2]+[\mathrm{Co}(\mathrm{en})_2\mathrm{Cl}_2]^+[Co(en)2​Cl2​]+ where en\mathrm{en}en = ethylenediamine, a bidentate ligand.

Since there are two en\mathrm{en}en ligands and two Cl−\mathrm{Cl}^-Cl− ligands, cobalt has coordination number: 2×2+2×1=62\times 2 + 2\times 1 = 62×2+2×1=6 So the complex is octahedral.

Thus, Reason (R) is correct.


  1. Find the geometrical isomers of [Co(en)2Cl2]+[\mathrm{Co}(\mathrm{en})_2\mathrm{Cl}_2]^+[Co(en)2​Cl2​]+

For an octahedral complex of type: [M(AA)2X2][M(AA)_2X_2][M(AA)2​X2​] where AAAAAA is a symmetric bidentate ligand like en, there are only two geometrical isomers:

  • cis: the two Cl\mathrm{Cl}Cl ligands are adjacent
  • trans: the two Cl\mathrm{Cl}Cl ligands are opposite

So the number of geometrical isomers is: 222 not 3.

Hence, Assertion (A) is incorrect.


  1. Why confusion may arise

The cis form of [Co(en)2Cl2]+[\mathrm{Co}(\mathrm{en})_2\mathrm{Cl}_2]^+[Co(en)2​Cl2​]+ is optically active and exists as two enantiomers (Δ\DeltaΔ and Λ\LambdaΛ), while the trans form is optically inactive.

So total stereoisomers are:

  • 2 optical isomers from cis
  • 1 trans form

Thus, total stereoisomers = 3.

But the question asks specifically for geometrical isomers, not stereoisomers. Therefore geometrical isomers are only 2.


  1. Evaluate the statements
  • Assertion (A): "The total number of geometrical isomers shown by [Co(en)2Cl2]+[\mathrm{Co}(\mathrm{en})_2\mathrm{Cl}_2]^+[Co(en)2​Cl2​]+ complex ion is three."
    False

  • Reason (R): "[Co(en)2Cl2]+[\mathrm{Co}(\mathrm{en})_2\mathrm{Cl}_2]^+[Co(en)2​Cl2​]+ complex ion has an octahedral geometry."
    True

Therefore, the correct option is: B\boxed{\text{B}}B​


  1. Comparison with stored answer

Stored correct answer: B
Derived answer: B

They agree.

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