- A(A) is correct but (R) is not correct
- B(A) is not correct but (R) is correct
- CBoth (A) and (R) are correct but (R) is not the correct explanation of (A)
- DBoth (A) and (R) are correct and (R) is the correct explanation of (A)
View written solutionFree
Correct answer: B
- Identify the complex and its geometry
The complex ion is where = ethylenediamine, a bidentate ligand.
Since there are two ligands and two ligands, cobalt has coordination number: So the complex is octahedral.
Thus, Reason (R) is correct.
- Find the geometrical isomers of
For an octahedral complex of type: where is a symmetric bidentate ligand like en, there are only two geometrical isomers:
- cis: the two ligands are adjacent
- trans: the two ligands are opposite
So the number of geometrical isomers is: not 3.
Hence, Assertion (A) is incorrect.
- Why confusion may arise
The cis form of is optically active and exists as two enantiomers ( and ), while the trans form is optically inactive.
So total stereoisomers are:
- 2 optical isomers from cis
- 1 trans form
Thus, total stereoisomers = 3.
But the question asks specifically for geometrical isomers, not stereoisomers. Therefore geometrical isomers are only 2.
- Evaluate the statements
-
Assertion (A): "The total number of geometrical isomers shown by complex ion is three."
False -
Reason (R): " complex ion has an octahedral geometry."
True
Therefore, the correct option is:
- Comparison with stored answer
Stored correct answer: B
Derived answer: B
They agree.
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