JEE MainChemistryCoordination CompoundsNumerical+4 / −1
Reaction of with excess ammonia and in the presence of results into a diamagnetic product. Number of electrons present in t2g-orbitals of the product is .
Numerical answer
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Correct answer: 6
- Identify the starting complex and metal oxidation state
The given complex is:
Since water is a neutral ligand, the oxidation state of cobalt is:
So the metal is .
Its electronic configuration is:
- Effect of excess ammonia and oxygen
Ammonia first replaces water ligands, and in presence of oxygen, cobalt(II) is oxidized to cobalt(III). The well-known product formed is an ammine complex of cobalt(III), such as:
- Why is the product diamagnetic?
For cobalt(III):
In an octahedral field with ligands, cobalt(III) forms a low-spin complex because has high crystal field splitting.
Thus the electron distribution is:
All electrons are paired, so the complex is diamagnetic, matching the statement in the question.
- Count electrons in orbitals
From
the number of electrons in the orbitals is:
Therefore, the required integer is:
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