Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Coordination Compounds question

2022 · 26 Jun · Shift 2 · Q23
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Coordination Compounds
  5. /2022 · 26 Jun · Shift 2 · Q23

Coordination Compounds question

2022 · 26 Jun · Shift 2 · Q23

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
Reaction of [Co(H2O)6]2+[Co(H_2O)_6]^{2+}[Co(H2​O)6​]2+ with excess ammonia and in the presence of oxygenoxygenoxygen results into a diamagnetic product. Number of electrons present in t2g-orbitals of the product is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 6

  1. Identify the starting complex and metal oxidation state

The given complex is: [Co(H2O)6]2+[Co(H_2O)_6]^{2+}[Co(H2​O)6​]2+

Since water is a neutral ligand, the oxidation state of cobalt is: x+6(0)=+2⇒x=+2x+6(0)=+2 \Rightarrow x=+2x+6(0)=+2⇒x=+2

So the metal is Co2+\text{Co}^{2+}Co2+.

Its electronic configuration is: Co:[Ar]3d74s2\text{Co}: [Ar]3d^74s^2Co:[Ar]3d74s2 Co2+:[Ar]3d7\text{Co}^{2+}: [Ar]3d^7Co2+:[Ar]3d7

  1. Effect of excess ammonia and oxygen

Ammonia first replaces water ligands, and in presence of oxygen, cobalt(II) is oxidized to cobalt(III). The well-known product formed is an ammine complex of cobalt(III), such as: [Co(NH3)6]3+[Co(NH_3)_6]^{3+}[Co(NH3​)6​]3+

  1. Why is the product diamagnetic?

For cobalt(III): Co3+=3d6\text{Co}^{3+} = 3d^6Co3+=3d6

In an octahedral field with NH3NH_3NH3​ ligands, cobalt(III) forms a low-spin complex because Co3+\text{Co}^{3+}Co3+ has high crystal field splitting.

Thus the electron distribution is: t2g6eg0t_{2g}^6 e_g^0t2g6​eg0​

All electrons are paired, so the complex is diamagnetic, matching the statement in the question.

  1. Count electrons in t2gt_{2g}t2g​ orbitals

From t2g6eg0t_{2g}^6 e_g^0t2g6​eg0​

the number of electrons in the t2gt_{2g}t2g​ orbitals is: 666

Therefore, the required integer is: 6\boxed{6}6​

PreviousNext

More from Coordination Compounds

  • The conductivity of a solution of complex with formula CoCl3​(NH3​)4​ corresponds to 1 : 1 electrolyte, then the primary valency of central metal ion is ​.2022 · Numerical
  • Fe3+ cation gives a prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of :2022 · MCQ
  • Low oxidation state of metals in their complexes are common when ligands :2022 · MCQ
  • Acidified potassium permanganate solution oxidises oxalic acid. The spin-only magnetic moment of the manganese product formed from the above reaction is ​ B.M. (Nearest integer)2022 · Numerical
  • Which of the following will have maximum stabilization due to crystal field?2022 · MCQ
  • Arrange the following coordination compounds in the increasing order of magnetic moments. (Atomic numbers : Mn = 25; Fe = 26) A. [FeF6​]3− B. [Fe(CN)6​]3− C. [MnCl6​]3− (high spin) D. [Mn(CN)6​]3− Choose the correct…2022 · MCQ
  • Total number of relatively more stable isomer(s) possible for octahedral complex [Cu(en)2​(SCN)2​] will be ​.2022 · Numerical
  • Match List I with List II Choose the correct answer from the options given below : Includes table2022 · MCQ