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Coordination Compounds question

2021 · 26 Aug · Shift 1 · Q18
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  5. /2021 · 26 Aug · Shift 1 · Q18

Coordination Compounds question

2021 · 26 Aug · Shift 1 · Q18

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The ratio of number of water molecules in Mohr's salt and potash alum is ‾×\underline{\hspace{2cm}}\times​× 10 −-− 1. (Integer answer)
Numerical answer
View written solutionFree

Correct answer: 5

  1. Write the formulas of the two compounds

    • Mohr's salt: FeSO4⋅(NH4)2SO4⋅6H2O\mathrm{FeSO_4\cdot (NH_4)_2SO_4\cdot 6H_2O}FeSO4​⋅(NH4​)2​SO4​⋅6H2​O So, number of water molecules in one formula unit =6= 6=6.

    • Potash alum: K2SO4⋅Al2(SO4)3⋅24H2O\mathrm{K_2SO_4\cdot Al_2(SO_4)_3\cdot 24H_2O}K2​SO4​⋅Al2​(SO4​)3​⋅24H2​O This is equivalent to: KAl(SO4)2⋅12H2O\mathrm{KAl(SO_4)_2\cdot 12H_2O}KAl(SO4​)2​⋅12H2​O Hence, number of water molecules in one formula unit of potash alum =24= 24=24 in the doubled form, or 121212 in the standard single formula unit form.

  2. Interpret the question

    In school/JEE chemistry, potash alum is usually taken as: KAl(SO4)2⋅12H2O\mathrm{KAl(SO_4)_2\cdot 12H_2O}KAl(SO4​)2​⋅12H2​O Therefore, compare water molecules as: 6:12=1:26 : 12 = 1 : 26:12=1:2

    So the ratio of number of water molecules in Mohr's salt and potash alum is: 612=12\frac{6}{12} = \frac{1}{2}126​=21​

  3. Use the given expression

    The question says the ratio is: ‾×10−1\underline{\hspace{2cm}} \times 10^{-1}​×10−1

    Let the required integer be nnn. Then: n×10−1=12n \times 10^{-1} = \frac{1}{2}n×10−1=21​

    So, n10=12\frac{n}{10} = \frac{1}{2}10n​=21​ n=5n = 5n=5

  4. Final answer

    5\boxed{5}5​

  5. Comparison with stored correct answer

    Stored correct answer = 555

    This matches the derived answer.

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