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Coordination Compounds question

2021 · 25 Jul · Shift 1 · Q16
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  5. /2021 · 25 Jul · Shift 1 · Q16

Coordination Compounds question

2021 · 25 Jul · Shift 1 · Q16

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
Three moles of AgClAgClAgCl get precipitated when one mole of an octahedral co-ordination compound with empirical formula CrCl3CrCl_3CrCl3​.3NH33NH_33NH3​.3H2O3H_2O3H2​O reacts with excess of silver nitrate. The number of chloride ions satisfying the secondary valency of the metal ion is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 0

  1. Interpret the data

The empirical formula is CrCl3⋅3NH3⋅3H2OCrCl_3\cdot 3NH_3\cdot 3H_2OCrCl3​⋅3NH3​⋅3H2​O and the complex is octahedral, so the coordination number of chromium is 666.

We are told that 1 mole of the compound gives 3 moles of AgClAgClAgCl with excess AgNO3AgNO_3AgNO3​.

This means all 3 chloride ions are present as ionisable chloride ions outside the coordination sphere, because only free Cl−Cl^-Cl− ions immediately precipitate with Ag+Ag^+Ag+: Ag++Cl−→AgCl↓Ag^+ + Cl^- \to AgCl\downarrowAg++Cl−→AgCl↓

So the complex must be of the form [Cr(NH3)x(H2O)y]Cl3[Cr(NH_3)_x(H_2O)_y]Cl_3[Cr(NH3​)x​(H2​O)y​]Cl3​ with x+y=6x+y=6x+y=6

Since the empirical formula contains 3NH33NH_33NH3​ and 3H2O3H_2O3H2​O, the inner sphere is [Cr(NH3)3(H2O)3]Cl3[Cr(NH_3)_3(H_2O)_3]Cl_3[Cr(NH3​)3​(H2​O)3​]Cl3​

  1. Primary and secondary valency
  • Primary valency of chromium is satisfied by ionisable anions outside the coordination sphere.
  • Secondary valency is satisfied by ligands directly coordinated to the metal inside the coordination sphere.

Here, the 3 chloride ions are all outside the coordination sphere, so none of the chloride ions are coordinated to chromium.

Therefore, the number of chloride ions satisfying the secondary valency of the metal ion is 000

  1. Final answer

The required integer is: 0\boxed{0}0​

  1. Comparison with stored answer

Stored correct answer = 000

This matches the derived answer.

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