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Coordination Compounds question

2018 · 15 Apr · Shift 2 · Q11
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Coordination Compounds question

2018 · 15 Apr · Shift 2 · Q11

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
The total number of possible isomers for square-planar [Pt(Cl)(NO2)(NO3)(SCN)]2−[Pt(Cl)(NO_2)(NO_3)(SCN)]^{2-}[Pt(Cl)(NO2​)(NO3​)(SCN)]2− is :
  1. A
    8
  2. B
    12
  3. C
    16
  4. D
    24
View written solutionFree

Correct answer: B

  1. Identify the types of isomerism possible

    The complex is square planar: [Pt(Cl)(NO2)(NO3)(SCN)]2−[Pt(Cl)(NO_2)(NO_3)(SCN)]^{2-}[Pt(Cl)(NO2​)(NO3​)(SCN)]2−

    It has four different monodentate ligands:

    • Cl−Cl^-Cl−
    • NO2−NO_2^-NO2−​
    • NO3−NO_3^-NO3−​
    • SCN−SCN^-SCN−

    Since all four ligands are different, a square-planar complex of type [Mabcd][Mabcd][Mabcd] has: 4!4=6\frac{4!}{4}=644!​=6 geometrical arrangements? Actually, for square planar complexes with four different ligands, the number of geometrical isomers equals the number of distinct choices of trans pairs.

    The number of ways to divide 4 ligands into 2 trans pairs is: 12(42)=3\frac{1}{2}\binom{4}{2}=321​(24​)=3

    So, ignoring linkage for the moment, there are 3 geometrical isomers.

  2. Check ligands capable of linkage isomerism

    Among the ligands:

    • Cl−Cl^-Cl− : not ambidentate
    • NO3−NO_3^-NO3−​ : usually taken as monodentate through O here, no linkage counted in this context
    • NO2−NO_2^-NO2−​ : ambidentate, can bind as
      • nitro: M−NO2M-NO_2M−NO2​
      • nitrito: M−ONOM-ONOM−ONO
    • SCN−SCN^-SCN− : ambidentate, can bind as
      • thiocyanato: M−SCNM-SCNM−SCN
      • isothiocyanato: M−NCSM-NCSM−NCS

    Thus there are 2 independent ambidentate ligands, each with 2 linkage possibilities.

    Hence total linkage possibilities: 2×2=42 \times 2 = 42×2=4

  3. Total number of isomers

    For each of the 3 square-planar geometrical arrangements, there are 4 linkage variants.

    Therefore total isomers: 3×4=123 \times 4 = 123×4=12

  4. Check options

    • A: 8 ❌
    • B: 12 ✅
    • C: 16 ❌
    • D: 24 ❌
  5. Final answer

    12\boxed{12}12​

So the correct option is B.

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