JEE MainChemistryCoordination CompoundsMCQ+4 / −1
In which of the following octahedral complexes of Co (at. no. 27), will the magnitude of be the highest?
- A
- B
- C
- D
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Correct answer: A
- Find the oxidation state and d-configuration of Co in each complex
For all given complexes, cobalt is in the +3 oxidation state:
- :
- :
- : is neutral, so
- : is neutral, so
So in every case, the metal ion is .
Cobalt has atomic number :
Thus,
Since the metal ion is the same in all complexes, the magnitude of depends mainly on the nature of the ligand.
- Use spectrochemical series
The octahedral crystal field splitting increases with ligand field strength.
Relevant part of the spectrochemical series is:
Thus, among the given ligands:
- is the strongest field ligand
- is stronger than
- Oxalate is weaker than both and
Therefore,
- Evaluate the options
- A: — strongest ligand , so largest
- B: — oxalate is weaker, so not highest
- C: — weaker than and
- D: — strong, but still weaker than
Hence, the highest value of is for:
So, option A is correct.
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