- Aone, tetrahedral
- Btwo, tetrahedral
- Cone, square planar
- Dtwo, square planar
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Correct answer: B
- Find the oxidation state of nickel in .
Since each ligand has charge ,
So the metal ion is .
- Write the electronic configuration of .
Nickel has ground-state configuration
Removing two electrons gives
So it is a system.
- Use the given information: the complex is paramagnetic.
The complex is with a uninegative monodentate ligand. Such 4-coordinate nickel(II) complexes with weak-field ligands like halides commonly form tetrahedral complexes.
For a tetrahedral field, crystal field splitting is small, so electrons remain unpaired as much as possible.
For a tetrahedral configuration, the arrangement gives 2 unpaired electrons.
- Check square planar possibility.
A square planar complex of is usually diamagnetic because electrons pair up completely in the lower-energy orbitals.
But the question says the complex is paramagnetic, so square planar is ruled out.
- Conclusion.
Thus, the complex has:
- 2 unpaired electrons
- tetrahedral geometry
So the correct option is B.
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