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Coordination Compounds question

2006 · Shift 0 · Q42
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Coordination Compounds question

2006 · Shift 0 · Q42

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Nickel (Z = 28) combines with a uninegative monodentate ligand X– to form a paramagnetic complex [NiX4]2−[NiX_4]^{2−}[NiX4​]2− . The number of unpaired electron(s) in the nickel and geometry of this complex ion are, respectively
  1. A
    one, tetrahedral
  2. B
    two, tetrahedral
  3. C
    one, square planar
  4. D
    two, square planar
View written solutionFree

Correct answer: B

  1. Find the oxidation state of nickel in [NiX4]2−[NiX_4]^{2-}[NiX4​]2−.

Since each ligand X−X^-X− has charge −1-1−1,

extOxidationstateofNi+4(−1)=−2 ext{Oxidation state of Ni} + 4(-1) = -2extOxidationstateofNi+4(−1)=−2 extOxidationstateofNi=+2 ext{Oxidation state of Ni} = +2extOxidationstateofNi=+2

So the metal ion is Ni2+\text{Ni}^{2+}Ni2+.

  1. Write the electronic configuration of Ni2+\text{Ni}^{2+}Ni2+.

Nickel (Z=28)(Z=28)(Z=28) has ground-state configuration

Ni:[Ar] 3d84s2\text{Ni}: [Ar] \, 3d^8 4s^2Ni:[Ar]3d84s2

Removing two electrons gives

Ni2+:[Ar] 3d8\text{Ni}^{2+}: [Ar] \, 3d^8Ni2+:[Ar]3d8

So it is a d8d^8d8 system.

  1. Use the given information: the complex is paramagnetic.

The complex is [NiX4]2−[NiX_4]^{2-}[NiX4​]2− with a uninegative monodentate ligand. Such 4-coordinate nickel(II) complexes with weak-field ligands like halides commonly form tetrahedral complexes.

For a tetrahedral field, crystal field splitting is small, so electrons remain unpaired as much as possible.

For a d8d^8d8 tetrahedral configuration, the arrangement gives 2 unpaired electrons.

  1. Check square planar possibility.

A square planar d8d^8d8 complex of Ni2+\text{Ni}^{2+}Ni2+ is usually diamagnetic because electrons pair up completely in the lower-energy orbitals.

But the question says the complex is paramagnetic, so square planar is ruled out.

  1. Conclusion.

Thus, the complex [NiX4]2−[NiX_4]^{2-}[NiX4​]2− has:

  • 2 unpaired electrons
  • tetrahedral geometry

So the correct option is B.

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