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Coordination Compounds question

2007 · Shift 0 · Q20
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Coordination Compounds question

2007 · Shift 0 · Q20

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Which one of the following has a square planar geometry?
  1. A
    [CoCl4]2−[CoCl_4]^{2-}[CoCl4​]2−
  2. B
    [FeCl4]2−[FeCl_4]^{2-}[FeCl4​]2−
  3. C
    [NiCl4]2−[NiCl_4]^{2-}[NiCl4​]2−
  4. D
    [PtCl4]2−[PtCl_4]^{2-}[PtCl4​]2−
View written solutionFree

Correct answer: D

  1. Determine the metal oxidation state and ddd-electron count

For all complexes, each Cl−Cl^-Cl− ligand has charge −1-1−1.

  • A: [CoCl4]2−[CoCl_4]^{2-}[CoCl4​]2− x+4(−1)=−2⇒x=+2x+4(-1)=-2 \Rightarrow x=+2x+4(−1)=−2⇒x=+2 So, Co2+Co^{2+}Co2+ has configuration: Co:[Ar]3d74s2⇒Co2+:[Ar]3d7Co: [Ar]3d^74s^2 \Rightarrow Co^{2+}:[Ar]3d^7Co:[Ar]3d74s2⇒Co2+:[Ar]3d7

  • B: [FeCl4]2−[FeCl_4]^{2-}[FeCl4​]2− x+4(−1)=−2⇒x=+2x+4(-1)=-2 \Rightarrow x=+2x+4(−1)=−2⇒x=+2 So, Fe2+Fe^{2+}Fe2+ is: Fe:[Ar]3d64s2⇒Fe2+:[Ar]3d6Fe:[Ar]3d^64s^2 \Rightarrow Fe^{2+}:[Ar]3d^6Fe:[Ar]3d64s2⇒Fe2+:[Ar]3d6

  • C: [NiCl4]2−[NiCl_4]^{2-}[NiCl4​]2− x+4(−1)=−2⇒x=+2x+4(-1)=-2 \Rightarrow x=+2x+4(−1)=−2⇒x=+2 So, Ni2+Ni^{2+}Ni2+ is: Ni:[Ar]3d84s2⇒Ni2+:[Ar]3d8Ni:[Ar]3d^84s^2 \Rightarrow Ni^{2+}:[Ar]3d^8Ni:[Ar]3d84s2⇒Ni2+:[Ar]3d8

  • D: [PtCl4]2−[PtCl_4]^{2-}[PtCl4​]2− x+4(−1)=−2⇒x=+2x+4(-1)=-2 \Rightarrow x=+2x+4(−1)=−2⇒x=+2 So, Pt2+Pt^{2+}Pt2+ is a 5d85d^85d8 ion.


  1. Use ligand strength and metal series to predict geometry

All complexes contain Cl−Cl^-Cl−, which is a weak field ligand.

For 4-coordinate complexes:

  • d6d^6d6, d7d^7d7 with weak ligands generally prefer tetrahedral geometry.
  • 3d83d^83d8 ions with weak ligands such as Ni2+Ni^{2+}Ni2+ usually form tetrahedral complexes, e.g. [NiCl4]2−[NiCl_4]^{2-}[NiCl4​]2−.
  • 5d85d^85d8 ions such as Pt2+Pt^{2+}Pt2+ strongly prefer square planar geometry because of larger crystal field splitting in 5d5d5d series.

  1. Evaluate each option
  • A: [CoCl4]2−[CoCl_4]^{2-}[CoCl4​]2− Co2+Co^{2+}Co2+ is 3d73d^73d7 with weak field Cl−Cl^-Cl− ligands Rightarrow RightarrowRightarrow tetrahedral, not square planar.

  • B: [FeCl4]2−[FeCl_4]^{2-}[FeCl4​]2− Fe2+Fe^{2+}Fe2+ is 3d63d^63d6 with weak field Cl−Cl^-Cl− ligands Rightarrow RightarrowRightarrow tetrahedral, not square planar.

  • C: [NiCl4]2−[NiCl_4]^{2-}[NiCl4​]2− Ni2+Ni^{2+}Ni2+ is 3d83d^83d8, but with weak field Cl−Cl^-Cl− and being a 3d3d3d metal, this complex is tetrahedral.

  • D: [PtCl4]2−[PtCl_4]^{2-}[PtCl4​]2− Pt2+Pt^{2+}Pt2+ is 5d85d^85d8 and characteristically forms square planar complexes.


  1. Final answer

The complex with square planar geometry is: [PtCl4]2−\boxed{[PtCl_4]^{2-}}[PtCl4​]2−​ So, the correct option is D.

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