JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Which one of the following has a square planar geometry?
- A
- B
- C
- D
View written solutionFree
Correct answer: D
- Determine the metal oxidation state and -electron count
For all complexes, each ligand has charge .
-
A: So, has configuration:
-
B: So, is:
-
C: So, is:
-
D: So, is a ion.
- Use ligand strength and metal series to predict geometry
All complexes contain , which is a weak field ligand.
For 4-coordinate complexes:
- , with weak ligands generally prefer tetrahedral geometry.
- ions with weak ligands such as usually form tetrahedral complexes, e.g. .
- ions such as strongly prefer square planar geometry because of larger crystal field splitting in series.
- Evaluate each option
-
A: is with weak field ligands tetrahedral, not square planar.
-
B: is with weak field ligands tetrahedral, not square planar.
-
C: is , but with weak field and being a metal, this complex is tetrahedral.
-
D: is and characteristically forms square planar complexes.
- Final answer
The complex with square planar geometry is: So, the correct option is D.
More from Coordination Compounds
- How many EDTA (ethylenediaminetetraacetic acid) molecules are required to make an octahedral complex with a ion?2006 · MCQ
- In , the Fe – C bond possesses :2006 · MCQ
- The IUPAC name for the complex Cl is2006 · MCQ
- Nickel (Z = 28) combines with a uninegative monodentate ligand X– to form a paramagnetic complex . The number of unpaired electron(s) in the nickel and geometry of this complex ion are, respectively2006 · MCQ
- The IUPAC name of the coordination compound is2005 · MCQ
- The oxidation state of Cr in is :2005 · MCQ
- Which of the following compounds shows optical isomerism?2005 · MCQ
- The value of the ‘spin only’ magnetic moment for one of the following configurations is 2.84 BM. The correct one is :2005 · MCQ