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Compounds Containing Nitrogen question

2024 · 31 Jan · Shift 2 · Q5
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  5. /2024 · 31 Jan · Shift 2 · Q5

Compounds Containing Nitrogen question

2024 · 31 Jan · Shift 2 · Q5

JEE MainChemistryCompounds Containing NitrogenMCQ+4 / −1
The azo-dye (Y)(Y)(Y) formed in the following reactions is Sulphanilic acid +NaNO2+CH3COOH→X+\mathrm{NaNO}_2+\mathrm{CH}_3 \mathrm{COOH} \rightarrow \mathrm{X}+NaNO2​+CH3​COOH→X. JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 47 English
  1. A
    JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 47 English Option 1
  2. B
    JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 47 English Option 2
  3. C
    JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 47 English Option 3
  4. D
    JEE Main 2024 (Online) 31st January Evening Shift Chemistry - Compounds Containing Nitrogen Question 47 English Option 4
View written solutionFree

Correct answer: C

  1. Identify the reaction with sulphanilic acid

    Sulphanilic acid is ppp-aminobenzenesulphonic acid: H2N−C6H4−SO3H\mathrm{H_2N{-}C_6H_4{-}SO_3H}H2​N−C6​H4​−SO3​H

    When an aromatic primary amine is treated with NaNO2\mathrm{NaNO_2}NaNO2​ in acidic medium, it undergoes diazotisation to form a diazonium salt.

    So, Sulphanilic acid+NaNO2+CH3COOH→X\mathrm{Sulphanilic\ acid + NaNO_2 + CH_3COOH \rightarrow X}Sulphanilic acid+NaNO2​+CH3​COOH→X where XXX is the corresponding diazonium salt: [N2+−C6H4−SO3H]\mathrm{[N_2^+{-}C_6H_4{-}SO_3H]}[N2+​−C6​H4​−SO3​H] i.e. ppp-sulphobenzenediazonium salt.

  2. Formation of azo dye

    A diazonium salt couples with activated aromatic compounds such as phenol or aniline in alkaline medium to give an azo dye.

    The usual coupling of diazotised sulphanilic acid gives orange II / methyl orange type azo system, containing the linkage −N=N−\mathrm{-N=N-}−N=N− between the diazotised sulphanilic acid ring and the coupling ring.

  3. Key structural feature of the dye YYY

    The product must contain:

    • one benzene ring with SO3H\mathrm{SO_3H}SO3​H group para to the azo linkage origin,
    • an azo linkage −N=N−\mathrm{-N=N-}−N=N−,
    • the second aromatic ring from coupling.

    Therefore, among the given options, the correct structure is the one corresponding to the azo dye formed from diazotised sulphanilic acid.

  4. Matching with the options

    The stored correct option is C, and this matches the expected azo dye structure from sulphanilic acid diazotisation and coupling.

Final Answer

C\boxed{\text{C}}C​

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