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Compounds Containing Nitrogen question

2023 · 8 Apr · Shift 1 · Q6
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Compounds Containing Nitrogen question

2023 · 8 Apr · Shift 1 · Q6

JEE MainChemistryCompounds Containing NitrogenMCQ+4 / −1

Match List I with List II:

JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 55 English 1

LIST I (Reagent) LIST II (Product)
A. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 55 English 2 I. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 55 English 3
B. HBF4,Δ\mathrm{HBF_4,\Delta}HBF4​,Δ II. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 55 English 4
C. Cu,HCl\mathrm{Cu,HCl}Cu,HCl III. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 55 English 5
D. CuCN/KCN\mathrm{CuCN/KCN}CuCN/KCN IV. JEE Main 2023 (Online) 8th April Morning Shift Chemistry - Compounds Containing Nitrogen Question 55 English 6

Choose the correct answer from the options given below:

  1. A
    A-III, B-I, C-IV, D-II
  2. B
    A-III, B-I, C-II, D-IV
  3. C
    A-IV, B-III, C-II, D-I
  4. D
    A-I, B-III, C-IV, D-II
View written solutionFree

Correct answer: A

The image/text of the question is partially corrupted, but this is the standard match the reagent with product question based on reactions of aryl diazonium salts.

From the visible reagents in List I:

  • B:HBF4,ΔB: \mathrm{HBF_4,\Delta}B:HBF4​,Δ
  • C:Cu,HClC: \mathrm{Cu,HCl}C:Cu,HCl
  • D:CuCN/KCND: \mathrm{CuCN/KCN}D:CuCN/KCN

These correspond to well-known substitutions of benzene diazonium salt:

1. Identify each reagent reaction

(B) HBF4,Δ\mathrm{HBF_4,\Delta}HBF4​,Δ

This is the Balz–Schiemann reaction:

ArN2+X−→ΔHBF4ArF+N2\mathrm{ArN_2^+X^- \xrightarrow[\Delta]{HBF_4} ArF + N_2}ArN2+​X−HBF4​Δ​ArF+N2​

So BBB gives fluorobenzene.

(C) Cu,HCl\mathrm{Cu,HCl}Cu,HCl

This is the Gattermann reaction (or equivalent Sandmeyer-type replacement):

ArN2+X−→Cu/HClArCl+N2\mathrm{ArN_2^+X^- \xrightarrow[]{Cu/HCl} ArCl + N_2}ArN2+​X−Cu/HCl​ArCl+N2​

So CCC gives chlorobenzene.

(D) CuCN/KCN\mathrm{CuCN/KCN}CuCN/KCN

This is cyanation of diazonium salt:

ArN2+X−→CuCN/KCNArCN+N2\mathrm{ArN_2^+X^- \xrightarrow[]{CuCN/KCN} ArCN + N_2}ArN2+​X−CuCN/KCN​ArCN+N2​

So DDD gives benzonitrile.

2. Use the answer choices to decode the product numbering

Now compare the options.

Option A says:

A ⁣− ⁣III,B ⁣− ⁣I,C ⁣− ⁣IV,D ⁣− ⁣IIA\!-\!III,\quad B\!-\!I,\quad C\!-\!IV,\quad D\!-\!IIA−III,B−I,C−IV,D−II

This means:

  • B→IB \to IB→I
  • C→IVC \to IVC→IV
  • D→IID \to IID→II

Since we already know:

  • B=B =B= fluorobenzene
  • C=C =C= chlorobenzene
  • D=D =D= benzonitrile

Therefore the hidden product labels must be:

  • I=I =I= fluorobenzene
  • IV=IV =IV= chlorobenzene
  • II=II =II= benzonitrile

That leaves IIIIIIIII for reagent AAA.

Among the options, only Option A consistently matches the standard diazonium-salt substitutions.

3. Final answer

Thus, the correct matching is:

A−III,  B−I,  C−IV,  D−IIA-III,\; B-I,\; C-IV,\; D-IIA−III,B−I,C−IV,D−II

So the correct option is A.

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