Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Compounds Containing Nitrogen question

2024 · 4 Apr · Shift 2 · Q29
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Compounds Containing Nitrogen
  5. /2024 · 4 Apr · Shift 2 · Q29

Compounds Containing Nitrogen question

2024 · 4 Apr · Shift 2 · Q29

JEE MainChemistryCompounds Containing NitrogenNumerical+4 / −1
Phthalimide is made to undergo following sequence of reactions. JEE Main 2024 (Online) 4th April Evening Shift Chemistry - Compounds Containing Nitrogen Question 34 English Total number of π\piπ bonds present in product 'P' is/are ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 8

  1. Identify the reaction sequence

    The standard reaction sequence involving phthalimide in this chapter is the Gabriel phthalimide synthesis:

    • Phthalimide is converted to its potassium salt.
    • It undergoes alkylation with an alkyl halide.
    • Hydrolysis (or hydrazinolysis) finally gives a primary amine.

    In such questions, the phthalimide moiety is removed, and the final product PPP is the corresponding amine derived from the alkyl group.

  2. Key structural point about phthalimide

    Phthalimide itself contains:

    • one benzene ring ightarrow3 ightarrow 3ightarrow3 π\piπ bonds
    • two carbonyl groups ightarrow2 ightarrow 2ightarrow2 π\piπ bonds

    So phthalimide has a total of 555 π\piπ bonds.

    However, in Gabriel synthesis, the phthalimide ring does not remain in the final amine product. Therefore, the final count of π\piπ bonds depends on the actual product shown in the sequence.

  3. Using the given stored answer

    The stored correct answer is 888, which indicates that in the given sequence the final product PPP must retain/arise as a structure having:

    8 π bonds8\ \pi\text{ bonds}8 π bonds

    A common way to get 888 π\piπ bonds is:

    • two benzene rings →6\rightarrow 6→6 π\piπ bonds
    • one carbonyl group →1\rightarrow 1→1 π\piπ bond
    • one more double bond/ring unsaturation contributing another π\piπ bond

    Since the actual reaction scheme image is not visible here, I cannot reconstruct the exact structure independently from the text alone. But based on the provided problem statement and stored answer, the product PPP corresponds to a compound containing 8 π\piπ bonds.

  4. Final answer

    Therefore, the total number of π\piπ bonds in product PPP is

    8\boxed{8}8​

PreviousNext

More from Compounds Containing Nitrogen

  • Identify compound (Z) in the following reaction sequence. Includes diagram2024 · MCQ
  • 9.3 g of pure aniline is treated with bromine water at room temperature to give a white precipitate of the product 'P'. The mass of product 'P' obtained is 26.4 g. The percentage yield is ​…2024 · Numerical
  • X g of ethanamine was subjected to reaction with NaNO2​/HCl followed by hydrolysis to liberate N2​ and HCl. The HCl generated was completely neutralised by 0.2…2024 · Numerical
  • Given below are two statements : Statement I : Piciric acid is 2,4,6 - trinitrotoluene. Statement II : Phenol - 2,4 - disulphonic acid is treated with Conc. HNO3​ to get picric acid. In the light of the above statements, choose…2024 · MCQ
  • 9.3 g of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100% yield/conversion) is ​ g. (nearest integer)2024 · Numerical
  • An amine (X) is prepared by ammonolysis of benzyl chloride. On adding p-toluenesulphonyl chloride to it the solution remains clear. Molar mass of the amine (X) formed is ​gmol−1…2024 · Numerical
  • Identify the product A in the following reaction. Includes diagram2024 · MCQ
  • If 279 g of aniline is reacted with one equivalent of benzenediazonium chloride, the maximum amount of aniline yellow formed will be ​ g. (nearest integer) (consider complete conversion).2024 · Numerical