JEE MainChemistryCompounds Containing NitrogenNumerical+4 / −1
In gaseous triethyl amine the " C N C " bond angle is degree.
Numerical answer
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Correct answer: 108
- Identify the molecule and geometry around nitrogen
Triethyl amine is .
The nitrogen atom is bonded to three carbon atoms and has one lone pair. So, around nitrogen there are 4 electron pairs:
- 3 bond pairs
- 1 lone pair
Hence, the electron pair geometry is approximately tetrahedral.
- Effect of lone pair on bond angle
For a perfect tetrahedral arrangement, the bond angle is
But a lone pair repels more strongly than bond pairs, so it compresses the bond angle between the three bonds.
Thus, the bond angle in a trialkyl amine is slightly less than .
- Known bond angle in gaseous triethyl amine
In gaseous triethyl amine, due to pyramidal nitrogen geometry, the bond angle is approximately
- Final answer
Therefore, the required bond angle is
degree.
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