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Compounds Containing Nitrogen question

2021 · 27 Jul · Shift 1 · Q19
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Compounds Containing Nitrogen question

2021 · 27 Jul · Shift 1 · Q19

JEE MainChemistryCompounds Containing NitrogenNumerical+4 / −1
In gaseous triethyl amine the "−-− C −-− N −-− C −-−" bond angle is ‾\underline{\hspace{2cm}}​ degree.
Numerical answer
View written solutionFree

Correct answer: 108

  1. Identify the molecule and geometry around nitrogen

Triethyl amine is (C2H5)3N(C_2H_5)_3N(C2​H5​)3​N.

The nitrogen atom is bonded to three carbon atoms and has one lone pair. So, around nitrogen there are 4 electron pairs:

  • 3 bond pairs
  • 1 lone pair

Hence, the electron pair geometry is approximately tetrahedral.

  1. Effect of lone pair on bond angle

For a perfect tetrahedral arrangement, the bond angle is 109.5∘109.5^\circ109.5∘

But a lone pair repels more strongly than bond pairs, so it compresses the bond angle between the three C−NC-NC−N bonds.

Thus, the C−N−CC-N-CC−N−C bond angle in a trialkyl amine is slightly less than 109.5∘109.5^\circ109.5∘.

  1. Known bond angle in gaseous triethyl amine

In gaseous triethyl amine, due to pyramidal sp3sp^3sp3 nitrogen geometry, the C−N−CC-N-CC−N−C bond angle is approximately 108∘108^\circ108∘

  1. Final answer

Therefore, the required bond angle is 108\boxed{108}108​

degree.

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