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Chemical Kinetics and Nuclear Chemistry question

2025 · 24 Jan · Shift 2 · Q21
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Chemical Kinetics and Nuclear Chemistry question

2025 · 24 Jan · Shift 2 · Q21

JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
Consider a complex reaction taking place in three steps with rate constants k1,k2\mathrm{k}_1, \mathrm{k}_2k1​,k2​ and k3\mathrm{k}_3k3​ respectively. The overall rate constant kkk is given by the expression k=k1k3k2k=\sqrt{\frac{k_1 k_3}{k_2}}k=k2​k1​k3​​​. If the activation energies of the three steps are 60, 30 and 10 kJ mol−110 \mathrm{~kJ} \mathrm{~mol}^{-1}10 kJ mol−1 respectively, then the overall energy of activation in kJmol−1\mathrm{kJ} \mathrm{mol}^{-1}kJmol−1 is ‾\underline{\hspace{2cm}}​ . (Nearest integer)
Numerical answer
View written solutionFree

Correct answer: 20

  1. Use the Arrhenius equation for each step:

ki=Aie−Ei/(RT)k_i = A_i e^{-E_i/(RT)}ki​=Ai​e−Ei​/(RT)

where EiE_iEi​ is the activation energy of step iii.

  1. Given:

k=k1k3k2k = \sqrt{\frac{k_1 k_3}{k_2}}k=k2​k1​k3​​​

Substitute the Arrhenius forms:

k=A1e−E1/(RT)⋅A3e−E3/(RT)A2e−E2/(RT)k = \sqrt{\frac{A_1 e^{-E_1/(RT)} \cdot A_3 e^{-E_3/(RT)}}{A_2 e^{-E_2/(RT)}}}k=A2​e−E2​/(RT)A1​e−E1​/(RT)⋅A3​e−E3​/(RT)​​

k=A1A3A2  e−(E1+E3−E2)/(RT)k = \sqrt{\frac{A_1A_3}{A_2} \; e^{-(E_1+E_3-E_2)/(RT)}}k=A2​A1​A3​​e−(E1​+E3​−E2​)/(RT)​

  1. Take the square root:

k=(A1A3A2)1/2e−E1+E3−E22RTk = \left(\frac{A_1A_3}{A_2}\right)^{1/2} e^{-\frac{E_1+E_3-E_2}{2RT}}k=(A2​A1​A3​​)1/2e−2RTE1​+E3​−E2​​

Compare with Arrhenius form:

k=Ae−Eoverall/(RT)k = A e^{-E_{\text{overall}}/(RT)}k=Ae−Eoverall​/(RT)

So,

Eoverall=E1+E3−E22E_{\text{overall}} = \frac{E_1 + E_3 - E_2}{2}Eoverall​=2E1​+E3​−E2​​

  1. Substitute the given activation energies:

E1=60,E2=30,E3=10(kJ mol−1)E_1 = 60, \quad E_2 = 30, \quad E_3 = 10 \quad (\text{kJ mol}^{-1})E1​=60,E2​=30,E3​=10(kJ mol−1)

Eoverall=60+10−302=402=20 kJ mol−1E_{\text{overall}} = \frac{60 + 10 - 30}{2} = \frac{40}{2} = 20 \text{ kJ mol}^{-1}Eoverall​=260+10−30​=240​=20 kJ mol−1

  1. Nearest integer:

20\boxed{20}20​

Comparison with stored correct answer:

Stored correct answer = 202020. This matches the derived answer.

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