JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
Consider a complex reaction taking place in three steps with rate constants and respectively. The overall rate constant is given by the expression . If the activation energies of the three steps are 60, 30 and respectively, then the overall energy of activation in is . (Nearest integer)
Numerical answer
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Correct answer: 20
- Use the Arrhenius equation for each step:
where is the activation energy of step .
- Given:
Substitute the Arrhenius forms:
- Take the square root:
Compare with Arrhenius form:
So,
- Substitute the given activation energies:
- Nearest integer:
Comparison with stored correct answer:
Stored correct answer = . This matches the derived answer.
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