JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
For a given reaction is related to as given in table. Given: Which of the following is true? A. The order of the reaction is . B. If is 1 M , then is C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M. D. is 800 min for Choose the correct answer from the options given below:- AA and C Only
- BA, B and D Only
- CA and B Only
- DC and D Only
View written solutionFree
Correct answer: B
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Use the half-life dependence on initial concentration
For an -th order reaction (),
So if then
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Infer relation from the given table
From the table, increases as , i.e.
Therefore,
Hence statement A is true.
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Find the proportionality constant
Since using the tabulated data, the constant comes out to be
Therefore, for ,
So statement B is true.
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Check statement C
Reaction order is a property of the rate law under given conditions; it does not change merely because concentration changes from to .
So statement C is false.
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Check statement D
For ,
Now,
Hence,
So statement D is true.
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Select the correct option
True statements: A, B, D
Therefore the correct option is:
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