JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
Consider the following reactions A ; B ; C ; D , The order of the above reactions are a, b, c, and d, respectively. The following graph is obtained when log[rate] vs. log[conc.] are plotted
Among the following, the correct sequence for the order of the reactions is :
Among the following, the correct sequence for the order of the reactions is :- Ad > b > a > c
- Bd > a > b > c
- Ca > b > c > d
- Dc > a > b > d
View written solutionFree
Correct answer: A
-
For a reaction with rate law taking logarithm gives:
-
Thus, in a plot of vs. :
- the slope of the line = order of reaction.
-
Therefore, to compare the orders , we only need to compare the slopes of the four lines corresponding to reactions:
- has order
- has order
- has order
- has order
-
From the given graph, the line for reaction has the greatest slope, followed by , then , and finally with the least slope.
-
Hence,
-
Comparing with the options:
- Option A: ✅
- Option B: ❌
- Option C: ❌
- Option D: ❌
Therefore, the correct answer is Option A.
More from Chemical Kinetics and Nuclear Chemistry
- The rate of a reaction decreased by 3.555 times when the temperature was changed from 40oC to 30oC. The activation energy (in kJ mol–1) of the reaction is . Take; R = 8.314 J mol–1 K–1 ln 3.555 = 1.2682020 · Numerical
- During the nuclear explosion, one of the products is 90Sr with half life of 6.93 years. If 1 g of 90Sr was absorbed in the bones of newly born baby in placed of Ca, how much time, in years, is required to reduce much time, in year,…2020 · Numerical
- For the reaction 2(g) + 2(g) (g) + 2(g) the observed rate expression is, rate = Kf[]2[]. The rate expression for the reverse reaction is :2020 · MCQ
- The rate of a certain biochemical reaction at physiological temperature (T) occurs 106 times faster with enzyme than without. The change in the activation energy upon adding enzyme is :2020 · MCQ
- Consider the following plots of rate constant versus for four different reactions. Which of the following orders is correct for the activation energies of these reactions? Includes diagram2020 · MCQ
- For the following reactions it was found that Ea is decreased by 30 kJ/mol in the…2020 · MCQ
- A sample of milk splits after 60 min. at 300 K and after 40 min. at 400 K when the population of lactobacillus acidophilus in it doubles. The activa tion energy (in kJ/ mol) for this process is closest to .…2020 · Numerical
- For the reaction 2A + B C, the values of initial rate at diffrent reactant concentrations are given in the table below. The rate law for the reaction is : Includes table2019 · MCQ