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Chemical Kinetics and Nuclear Chemistry question

2020 · 7 Jan · Shift 1 · Q3
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Chemical Kinetics and Nuclear Chemistry question

2020 · 7 Jan · Shift 1 · Q3

JEE MainChemistryChemical Kinetics and Nuclear ChemistryNumerical+4 / −1
During the nuclear explosion, one of the products is 90Sr with half life of 6.93 years. If 1 μ\muμ g of 90Sr was absorbed in the bones of newly born baby in placed of Ca, how much time, in years, is required to reduce much time, in year, is required to reduce it by 90% if it not lost metabolically.
Numerical answer
View written solutionFree

Correct answer: 23TO23.03

  1. Given data
  • Half-life of 90Sr^{90}\text{Sr}90Sr: t1/2=6.93 yearst_{1/2} = 6.93\ \text{years}t1/2​=6.93 years
  • Initial amount absorbed: N0=1 μgN_0 = 1\ \mu gN0​=1 μg
  • We need the time required to reduce by 90%.

So, 10% of the original amount remains: N=0.1N0N = 0.1N_0N=0.1N0​


  1. Use radioactive decay law

For radioactive decay, N=N0(12)t/t1/2N = N_0\left(\frac{1}{2}\right)^{t/t_{1/2}}N=N0​(21​)t/t1/2​

Substitute N=0.1N0N = 0.1N_0N=0.1N0​: 0.1N0=N0(12)t/6.930.1N_0 = N_0\left(\frac{1}{2}\right)^{t/6.93}0.1N0​=N0​(21​)t/6.93

Cancel N0N_0N0​: 0.1=(12)t/6.930.1 = \left(\frac{1}{2}\right)^{t/6.93}0.1=(21​)t/6.93


  1. Take logarithm

Taking logarithm on both sides, log⁡(0.1)=t6.93log⁡(12)\log(0.1) = \frac{t}{6.93}\log\left(\frac{1}{2}\right)log(0.1)=6.93t​log(21​)

Thus, t=6.93⋅log⁡(0.1)log⁡(1/2)t = 6.93\cdot \frac{\log(0.1)}{\log(1/2)}t=6.93⋅log(1/2)log(0.1)​

Now, log⁡(0.1)=−1\log(0.1) = -1log(0.1)=−1 log⁡(1/2)=−0.3010\log(1/2) = -0.3010log(1/2)=−0.3010

So, t=6.93⋅−1−0.3010t = 6.93\cdot \frac{-1}{-0.3010}t=6.93⋅−0.3010−1​ t=6.93⋅3.322t = 6.93\cdot 3.322t=6.93⋅3.322 t≈23.02 yearst \approx 23.02\ \text{years}t≈23.02 years


  1. Final answer

The time required to reduce the amount of 90Sr^{90}\text{Sr}90Sr by 90% is 23 years\boxed{23\ \text{years}}23 years​ (more precisely, 23.02 to 23.03 years\boxed{23.02\text{ to }23.03\ \text{years}}23.02 to 23.03 years​)


  1. Comparison with stored answer

Stored correct answer: 23 to 23.03

Our calculated answer is 23.02–23.0323.02\text{–}23.0323.02–23.03 years, which matches the stored answer range.

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