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Chemical Kinetics and Nuclear Chemistry question

2003 · Shift 0 · Q39
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Chemical Kinetics and Nuclear Chemistry question

2003 · Shift 0 · Q39

JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
The half-life of a radioactive isotope is three hours. If the initial mass of the isotope were 256 g, the mass of it remaining undecayed after 18 hours would be
  1. A
    8.0 g
  2. B
    12.0 g
  3. C
    16.0 g
  4. D
    4.0 g
View written solutionFree

Correct answer: D

  1. Given data

    • Half-life, t1/2=3t_{1/2} = 3t1/2​=3 hours
    • Initial mass, N0=256 gN_0 = 256\,\text{g}N0​=256g
    • Total time elapsed, t=18t = 18t=18 hours
  2. Find the number of half-lives elapsed n=tt1/2=183=6n = \frac{t}{t_{1/2}} = \frac{18}{3} = 6n=t1/2​t​=318​=6

  3. Use the radioactive decay formula After nnn half-lives, the remaining mass is: N=N0(12)nN = N_0\left(\frac{1}{2}\right)^nN=N0​(21​)n

    Substituting the values: N=256(12)6N = 256\left(\frac{1}{2}\right)^6N=256(21​)6

  4. Calculate (12)6=164\left(\frac{1}{2}\right)^6 = \frac{1}{64}(21​)6=641​ So, N=256×164=4 gN = 256 \times \frac{1}{64} = 4\,\text{g}N=256×641​=4g

  5. Match with the options

    • A: 8.0 g8.0\,\text{g}8.0g
    • B: 12.0 g12.0\,\text{g}12.0g
    • C: 16.0 g16.0\,\text{g}16.0g
    • D: 4.0 g4.0\,\text{g}4.0g

    Therefore, the correct option is D.

  6. Comparison with stored correct answer Stored correct answer: D

    My derived answer also gives D. So they agree.

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