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Chemical Kinetics and Nuclear Chemistry question

2002 · Shift 0 · Q40
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Chemical Kinetics and Nuclear Chemistry question

2002 · Shift 0 · Q40

JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
If half-life of a substance is 5 yrs, then the total amount of substance left after 15 years, when initial amount is 64 grams is
  1. A
    16 grams
  2. B
    2 grams
  3. C
    32 grams
  4. D
    8 grams
View written solutionFree

Correct answer: D

  1. Use the half-life concept

    The half-life is the time in which the amount of substance becomes half of its previous value.

    Given:

    • Half-life =5= 5=5 years
    • Initial amount N0=64N_0 = 64N0​=64 g
    • Total time t=15t = 15t=15 years
  2. Find number of half-lives elapsed

    n=tt1/2=155=3n = \frac{t}{t_{1/2}} = \frac{15}{5} = 3n=t1/2​t​=515​=3

    So, in 151515 years, the substance undergoes 333 half-lives.

  3. Apply repeated halving

    After 1 half-life: 64→32 g64 \to 32 \text{ g}64→32 g

    After 2 half-lives: 32→16 g32 \to 16 \text{ g}32→16 g

    After 3 half-lives: 16→8 g16 \to 8 \text{ g}16→8 g

    Therefore, amount left after 151515 years is 8 g8 \text{ g}8 g

  4. Using formula check

    N=N0(12)n=64(12)3=64⋅18=8 gN = N_0\left(\frac{1}{2}\right)^n = 64\left(\frac{1}{2}\right)^3 = 64 \cdot \frac{1}{8} = 8 \text{ g}N=N0​(21​)n=64(21​)3=64⋅81​=8 g

  5. Evaluate options

    • A: 161616 g — incorrect
    • B: 222 g — incorrect
    • C: 323232 g — incorrect
    • D: 888 g — correct

Hence, the correct answer is Option D.

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