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Chemical Bonding and Molecular Structure question

2011 · Shift 0 · Q24
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Chemical Bonding and Molecular Structure question

2011 · Shift 0 · Q24

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The structure of IF7IF_7IF7​ is :
  1. A
    trigonal bipyramid
  2. B
    octahedral
  3. C
    pentagonal bipyramid
  4. D
    square pyramid
View written solutionFree

Correct answer: C

  1. Count the electron pairs around iodine in IF7IF_7IF7​

    • Iodine is the central atom.
    • It is bonded to 777 fluorine atoms.
    • Thus, there are 777 bond pairs around iodine and no lone pair on the central atom.
  2. Apply VSEPR theory

    For a central atom with steric number 777 (i.e. 777 regions of electron density), the arrangement that minimizes repulsion is: Pentagonal bipyramidal\text{Pentagonal bipyramidal}Pentagonal bipyramidal

  3. Match with the given options

    • A: trigonal bipyramid →\rightarrow→ steric number 555
    • B: octahedral →\rightarrow→ steric number 666
    • C: pentagonal bipyramid →\rightarrow→ steric number 777
    • D: square pyramid →\rightarrow→ derived from octahedral with one lone pair

    Therefore, the correct structure of IF7IF_7IF7​ is: Pentagonal bipyramid\boxed{\text{Pentagonal bipyramid}}Pentagonal bipyramid​

  4. Compare with stored answer

    • Derived answer: C
    • Stored correct answer: C

    Both match.

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