- Aion-dipole interaction
- BLondon force
- Chydrogen bond
- Dion-ion interaction
View written solutionFree
Correct answer: A
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Identify the distance dependence of common intermolecular interactions
We compare how the potential energy of different interactions varies with intermolecular distance :
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Ion-ion interaction:
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Ion-dipole interaction: The potential of an ion with a permanent dipole varies as and the corresponding force varies as .
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London force (dispersion):
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Hydrogen bond: Hydrogen bonding does not have a simple standard inverse-cube law; it is a special directional dipole-related interaction, not generally expressed as .
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Check the wording carefully
The question asks for the intermolecular interaction dependent on the inverse cube of distance.
Among standard interactions:
- ion-ion
- London force
- hydrogen bond no standard dependence
- ion-dipole is the only one associated with inverse-cube dependence in the interaction analysis often discussed via force dependence.
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Evaluate options
- A: ion-dipole interaction — closest and correct for inverse-cube dependence
- B: London force — incorrect, depends on
- C: hydrogen bond — incorrect
- D: ion-ion interaction — incorrect, depends on
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Derived answer
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Compare with stored correct answer
Stored answer is C, but hydrogen bonding is not characterized by an inverse-cube distance dependence. The best correct choice is A.
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