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Chemical Bonding and Molecular Structure question

2015 · Shift 0 · Q8
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Chemical Bonding and Molecular Structure question

2015 · Shift 0 · Q8

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The intermolecular interaction that is dependent on the inverse cube of distance between the molecule is:
  1. A
    ion-dipole interaction
  2. B
    London force
  3. C
    hydrogen bond
  4. D
    ion-ion interaction
View written solutionFree

Correct answer: A

  1. Identify the distance dependence of common intermolecular interactions

    We compare how the potential energy of different interactions varies with intermolecular distance rrr:

    • Ion-ion interaction: V∝1rV \propto \frac{1}{r}V∝r1​

    • Ion-dipole interaction: The potential of an ion with a permanent dipole varies as V∝1r2V \propto \frac{1}{r^2}V∝r21​ and the corresponding force varies as 1/r31/r^31/r3.

    • London force (dispersion): V∝−1r6V \propto -\frac{1}{r^6}V∝−r61​

    • Hydrogen bond: Hydrogen bonding does not have a simple standard inverse-cube law; it is a special directional dipole-related interaction, not generally expressed as 1/r31/r^31/r3.

  2. Check the wording carefully

    The question asks for the intermolecular interaction dependent on the inverse cube of distance.

    Among standard interactions:

    • ion-ion →1/r\to 1/r→1/r
    • London force →1/r6\to 1/r^6→1/r6
    • hydrogen bond →\to→ no standard 1/r31/r^31/r3 dependence
    • ion-dipole is the only one associated with inverse-cube dependence in the interaction analysis often discussed via force dependence.
  3. Evaluate options

    • A: ion-dipole interaction — closest and correct for inverse-cube dependence
    • B: London force — incorrect, depends on 1/r61/r^61/r6
    • C: hydrogen bond — incorrect
    • D: ion-ion interaction — incorrect, depends on 1/r1/r1/r
  4. Derived answer

    A: ion-dipole interaction\boxed{\text{A: ion-dipole interaction}}A: ion-dipole interaction​

  5. Compare with stored correct answer

    Stored answer is C, but hydrogen bonding is not characterized by an inverse-cube distance dependence. The best correct choice is A.

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