JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizinig order of the polarizing power of the cationic species, , , , ?
- A< < <
- B< < <
- C< < <
- D< < <
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Correct answer: B
-
Concept used: Fajans' rule
The polarizing power of a cation depends on its charge/size ratio.- Higher positive charge greater polarizing power
- Smaller ionic size greater polarizing power
So, polarizing power increases with:
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Compare the given cations
Given species:
- has only charge and relatively large size, so it has the least polarizing power.
- Among the doubly charged cations, smaller size means greater polarizing power.
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Size trend
Ionic sizes decrease roughly as:
Since all three have the same charge , their polarizing power increases as size decreases:
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Combine both effects
Since has lower charge and larger size than the others, it comes first:
-
Match with options
This corresponds to Option B.
Final Answer:
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