Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Chemical Bonding and Molecular Structure question

2007 · Shift 0 · Q34
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Chemical Bonding and Molecular Structure
  5. /2007 · Shift 0 · Q34

Chemical Bonding and Molecular Structure question

2007 · Shift 0 · Q34

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizinig order of the polarizing power of the cationic species, K+K^+K+, Ca2+Ca^{2+}Ca2+, Mg2+Mg^{2+}Mg2+, Be2+Be^{2+}Be2+?
  1. A
    Mg2+Mg^{2+}Mg2+ < Be2+Be^{2+}Be2+ < K+K^+K+ < Ca2+Ca^{2+}Ca2+
  2. B
    K+K^+K+ < Ca2+Ca^{2+}Ca2+ < Mg2+Mg^{2+}Mg2+ < Be2+Be^{2+}Be2+
  3. C
    Be2+Be^{2+}Be2+ < K+K^+K+ < Ca2+Ca^{2+}Ca2+ < Mg2+Mg^{2+}Mg2+
  4. D
    Ca2+Ca^{2+}Ca2+ < Mg2+Mg^{2+}Mg2+ < Be2+Be^{2+}Be2+ < K+K^+K+
View written solutionFree

Correct answer: B

  1. Concept used: Fajans' rule
    The polarizing power of a cation depends on its charge/size ratio.

    • Higher positive charge ⇒\Rightarrow⇒ greater polarizing power
    • Smaller ionic size ⇒\Rightarrow⇒ greater polarizing power

    So, polarizing power increases with: Polarizing power∝chargesize\text{Polarizing power} \propto \frac{\text{charge}}{\text{size}}Polarizing power∝sizecharge​

  2. Compare the given cations

    Given species: K+, Ca2+, Mg2+, Be2+K^+,\ Ca^{2+},\ Mg^{2+},\ Be^{2+}K+, Ca2+, Mg2+, Be2+

    • K+K^+K+ has only +1+1+1 charge and relatively large size, so it has the least polarizing power.
    • Among the doubly charged cations, smaller size means greater polarizing power.
  3. Size trend

    Ionic sizes decrease roughly as: Ca2+>Mg2+>Be2+Ca^{2+} > Mg^{2+} > Be^{2+}Ca2+>Mg2+>Be2+

    Since all three have the same charge +2+2+2, their polarizing power increases as size decreases: Ca2+<Mg2+<Be2+Ca^{2+} < Mg^{2+} < Be^{2+}Ca2+<Mg2+<Be2+

  4. Combine both effects

    Since K+K^+K+ has lower charge and larger size than the others, it comes first: K+<Ca2+<Mg2+<Be2+K^+ < Ca^{2+} < Mg^{2+} < Be^{2+}K+<Ca2+<Mg2+<Be2+

  5. Match with options

    This corresponds to Option B.

Final Answer: K+<Ca2+<Mg2+<Be2+K^+ < Ca^{2+} < Mg^{2+} < Be^{2+}K+<Ca2+<Mg2+<Be2+

PreviousNext

More from Chemical Bonding and Molecular Structure

  • Which of the following species exhibits the diamagnetic behaviour?2007 · MCQ
  • Which of the following molecules/ions does not contain unpaired electrons?2006 · MCQ
  • In which of the following molecules/ions are all the bonds not equal?2006 · MCQ
  • The decreasing values of bond angles from NH3​ (106o) to SbH3​ (91o ) down group-15 of the periodic table is due to2006 · MCQ
  • Which one of the following species is diamagnetic in nature?2005 · MCQ
  • Lattice energy of an ionic compounds depends upon2005 · MCQ
  • The correct order of bond angles (smallest first) in H2​S, NH3​, BF3​ and SiH4​ is2004 · MCQ
  • The bond order in NO is 2.5 while that in NO+ is 3. Which of the following statements is true for these two species?2004 · MCQ