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Biomolecules question

2025 · 28 Jan · Shift 2 · Q6
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Biomolecules question

2025 · 28 Jan · Shift 2 · Q6

JEE MainChemistryBiomoleculesMCQ+4 / −1

Match List-I with List-II.

List - I (Saccharides) List - II (Glycosidic-linkages found)
(A) Sucrose (I) α 1 −-− 4
(B) Maltose (II) α 1 −-− 4 and α 1 −-− 6
(C) Lactose (III) α 1 −-−β 2
(D) Amylopectin (IV) β 1 −-− 4

Choose the correct answer from the options given below :

  1. A
    (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
  2. B
    (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
  3. C
    (A)-(II), (B)-(IV), (C)-(III), (D)-(I)
  4. D
    (A)-(IV), (B)-(II), (C)-(I), (D)-(III)
View written solutionFree

Correct answer: A

  1. Identify the glycosidic linkage in each saccharide:

    (A) Sucrose

    • Sucrose is formed from α\alphaα-D-glucose and β\betaβ-D-fructose.
    • The linkage is between C-1 of glucose and C-2 of fructose.
    • Hence, linkage = α1−β2\alpha 1-\beta 2α1−β2
    • So, (A) →\to→ (III)

    (B) Maltose

    • Maltose consists of two glucose units.
    • The glycosidic bond is α(1→4)\alpha(1\to 4)α(1→4).
    • So, (B) →\to→ (I)

    (C) Lactose

    • Lactose consists of galactose and glucose.
    • The glycosidic bond is β(1→4)\beta(1\to 4)β(1→4).
    • So, (C) →\to→ (IV)

    (D) Amylopectin

    • Amylopectin is a branched polymer of glucose.
    • It contains α(1→4)\alpha(1\to 4)α(1→4) linkages in the main chain and α(1→6)\alpha(1\to 6)α(1→6) at branch points.
    • So, (D) →\to→ (II)
  2. Final matching:

    (A)−(III),(B)−(I),(C)−(IV),(D)−(II)(A)-(III),\quad (B)-(I),\quad (C)-(IV),\quad (D)-(II)(A)−(III),(B)−(I),(C)−(IV),(D)−(II)
  3. Compare with options:

    • This corresponds to Option A.
  4. Comparison with stored correct answer:

    • Stored correct answer = A
    • Derived answer = A
    • Therefore, they agree.
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